Abstract
Chiral dendrimers bearing four or twelve chiral β-amino alcohols on the hyperbranched flexible carbosilane chain-ends act as efficient chiral catalysts for the enantioselective addition of dialkylzinc to aldehydes to afford enantiomerically enriched sec-alcohols with up to 93% e.e.
| Original language | English |
|---|---|
| Pages (from-to) | 805-808 |
| Number of pages | 4 |
| Journal | Tetrahedron Asymmetry |
| Volume | 13 |
| Issue number | 8 |
| DOIs | |
| Publication status | Published - 2002 May 15 |
ASJC Scopus subject areas
- Catalysis
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry
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Sato, I., Kodaka, R., Hosoi, K., & Soai, K. (2002). Highly enantioselective addition of dialkylzincs to aldehydes using dendritic chiral catalysts with flexible carbosilane backbones. Tetrahedron Asymmetry, 13(8), 805-808. https://doi.org/10.1016/S0957-4166(02)00203-3