Highly enantiomeric supramolecular [4 + 4] photocyclodimerization of 2-anthracenecarboxylate mediated by human serum albumin

Masaki Nishijima, Takehiko Wada, Tadashi Mori, Tamara C.S. Pace, Cornelia Bohne, Yoshihisa Inoue

Research output: Contribution to journalArticlepeer-review

105 Citations (Scopus)

Abstract

Photoirradiation at λ > 320 nm of 2-anthracenecarboxylate bound to human serum albumin in an aqueous buffer solution at 5 °C gave syn head-to-tail cyclodimer 2 in 82% ee and anti head-to-head cyclodimer 3 in 90% ee.

Original languageEnglish
Pages (from-to)3478-3479
Number of pages2
JournalJournal of the American Chemical Society
Volume129
Issue number12
DOIs
Publication statusPublished - 2007 Mar 28
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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