Highly compressed two-dimensional form of water at ambient conditions

Sarp Kaya, Daniel Schlesinger, Susumu Yamamoto, John T. Newberg, Hendrik Bluhm, Hirohito Ogasawara, Tom Kendelewicz, Gordon E. Brown, Lars G.M. Pettersson, Anders Nilsson

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Abstract

The structure of thin-film water on a BaF 2 (111) surface under ambient conditions was studied using X-ray absorption spectroscopy from ambient to supercooled temperatures at relative humidity up to 95%. No hexagonal ice-like structure was observed in spite of the expected templating effect of the lattice-matched (111) surface. The oxygen K-edge X-ray absorption spectrum of liquid thin-film water on BaF 2 exhibits, at all temperatures, a strong resemblance to that of high-density phases for which the observed spectroscopic features correlate linearly with the density. Surprisingly, the highly compressed, high-density thin-film liquid water is found to be stable from ambient (300 K) to supercooled (259 K) temperatures, although a lower-density liquid would be expected at supercooled conditions. Molecular dynamics simulations indicate that the first layer water on BaF 2 (111) is indeed in a unique local structure that resembles high-density water, with a strongly collapsed second coordination shell.

Original languageEnglish
Article number1074
JournalScientific reports
Volume3
DOIs
Publication statusPublished - 2013

ASJC Scopus subject areas

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    Kaya, S., Schlesinger, D., Yamamoto, S., Newberg, J. T., Bluhm, H., Ogasawara, H., Kendelewicz, T., Brown, G. E., Pettersson, L. G. M., & Nilsson, A. (2013). Highly compressed two-dimensional form of water at ambient conditions. Scientific reports, 3, [1074]. https://doi.org/10.1038/srep01074