High temperature proton NMR study of yttrium doped barium cerates

Hideki Maekawa, Yoshitaka Ukei, Kai Morota, Naohito Kashii, Junichi Kawamura, Tsutomu Yamamura

Research output: Contribution to journalArticlepeer-review

18 Citations (Scopus)

Abstract

The mobility of protons in BaCe1-xYxO 3-δ perovskite (x=0.01 to 0.10) was investigated by high temperature 1H NMR spin-lattice relaxation time (T1) and ac conductivity measurements. The temperature variation of T1 was obtained from room temperature to 1073 K. The absolute magnitude of T 1 shows a complex dependence on doping concentration. However, the shape of the temperature dependence of T1 was independent of the doping concentration, suggesting the absence of major differences of the proton hopping mechanism on doping level of this material. The measured conductivity was well reproduced by a simple hopping model using correlation times of proton migration and proton concentrations estimated from the NMR measurement.

Original languageEnglish
Pages (from-to)73-77
Number of pages5
JournalSolid State Communications
Volume130
Issue number1-2
DOIs
Publication statusPublished - 2004 Apr 1

Keywords

  • A. Nanostructures
  • B. Chemical synthesis
  • D. Electronic transport
  • E. Neutron scattering
  • E. Nuclear resonance

ASJC Scopus subject areas

  • Chemistry(all)
  • Condensed Matter Physics
  • Materials Chemistry

Fingerprint Dive into the research topics of 'High temperature proton NMR study of yttrium doped barium cerates'. Together they form a unique fingerprint.

Cite this