High sinterability of planetary-bead-milled barium zirconate

Takaaki Sakai, Hiroshige Matsumoto, Yasuhiko Sato, Junji Hyodo, Naoki Ito, Shin Ichi Hashimoto, Tatsumi Ishihara

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

Sintering is an important process in the preparation of solid electrolytes. Milling of the precursor powders general-ly increases their sinterability, and thus, an effective milling method is important to obtain dense electrolytes. In this study, we demonstrate that planetary bead milling provides nanosize precursor powders with markedly high sinterability. For BaZrO3, a proton-conducting oxide with low sinterability in its unmilled state, planetary bead milling with 0.2 mm beads enables a reduction in sintering temperature to 1400-1500 °C, which is 300-400 °C lower than usual. We also discuss the effect of bead milling on microstructure and conductivity.

Original languageEnglish
Pages (from-to)876-878
Number of pages3
JournalElectrochemistry
Volume77
Issue number10
DOIs
Publication statusPublished - 2009 Oct

Keywords

  • Barium zirconate
  • Low-temperature sintering
  • Planetary bead mill
  • Proton conductor
  • Solid electrolyte

ASJC Scopus subject areas

  • Electrochemistry

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    Sakai, T., Matsumoto, H., Sato, Y., Hyodo, J., Ito, N., Hashimoto, S. I., & Ishihara, T. (2009). High sinterability of planetary-bead-milled barium zirconate. Electrochemistry, 77(10), 876-878. https://doi.org/10.5796/electrochemistry.77.876