High Proton Conductivity in Ba5Er2Al2ZrO13, a Hexagonal Perovskite-Related Oxide with Intrinsically Oxygen-Deficient Layers

Taito Murakami, James R. Hester, Masatomo Yashima

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1 Citation (Scopus)

Abstract

For the development of proton-based electrolytes, high proton conductivity at intermediate temperatures (300-600 °C) is crucial, but the available materials have been confined to a limited number of the structure families, such as cubic perovskites. Herein, we report Ba5Er2Al2ZrO13, a hexagonal perovskite-related oxide, as a new class of proton conductors exhibiting higher conductivities than 10-3 S cm-1 between 300 and 1200 °C. The protons as charge carriers are found to exist in the inherently oxygen-deficient h′ layer of Ba5Er2Al2ZrO13, which are supported by Rietveld analysis of neutron-diffraction data, bond-valence-based energy calculations, and thermogravimetric analysis. Our discovery of a new structure family of proton conductors with the inherently oxygen-deficient h′ layer offers a strategy in designing superior proton conductors based on hexagonal perovskite-related oxides.

Original languageEnglish
Pages (from-to)11653-11657
Number of pages5
JournalJournal of the American Chemical Society
Volume142
Issue number27
DOIs
Publication statusPublished - 2020 Jul 8
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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