High-Performance Thermomagnetic Generators Based on Heusler Alloy Films

Marcel Gueltig, Frank Wendler, Hinnerk Ossmer, Makoto Ohtsuka, Hiroyuki Miki, Toshiyuki Takagi, Manfred Kohl

Research output: Contribution to journalArticlepeer-review

29 Citations (Scopus)

Abstract

Recent developments on Heusler alloys including Ni–Mn–X and Ni–Co–Mn–X (X = Ga, In, Sn,…) demonstrate multiferroic phase transformations with large abrupt changes in lattice parameters of several percent and corresponding abrupt changes in ferromagnetic ordering near the transition temperatures. These materials enable a new generation of thermomagnetic generators that convert heat to electricity within a small temperature difference below 5 K. While thermodynamic calculations on this energy conversion method predict a power density normalized to material volume of up to 300 mW cm−3, experimental results have been in the range of µW cm−3. Challenges are related to the development of materials with bulk-like single-crystal properties as well as geometries with large surface-to-volume ratio for rapid heat exchange. This study demonstrates efficient thermomagnetic generation via resonant actuation of freely movable thin-film devices of the Heusler alloy Ni–Mn–Ga with unprecedented power density of 118 mW cm−3 that compares favorably with the best thermoelectric generators. Due to the large temperature-dependent change of magnetization of the films, a periodic temperature change of only 3 K is required for operation. The duration of thermomagnetic duty cycle is only about 12 ms, which matches with the period of oscillatory motion.

Original languageEnglish
JournalAdvanced Energy Materials
Volume7
Issue number5
DOIs
Publication statusPublished - 2017 Mar 8

Keywords

  • actuators
  • energy harvesting
  • magnetic films
  • martensitic transformation
  • shape memory films

ASJC Scopus subject areas

  • Renewable Energy, Sustainability and the Environment
  • Materials Science(all)

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