High-performance symmetric sodium-ion batteries using a new, bipolar O3-type material, Na0.8Ni0.4Ti0.6O2

Shaohua Guo, Haijun Yu, Pan Liu, Yang Ren, Tao Zhang, Mingwei Chen, Masayoshi Ishida, Haoshen Zhou

    Research output: Contribution to journalArticle

    140 Citations (Scopus)

    Abstract

    Based on low-cost and rich resources, sodium-ion batteries have been regarded as a promising candidate for next-generation energy storage batteries in the large-scale energy applications of renewable energy and smart grids. However, there are some critical drawbacks limiting its application, such as safety and stability problems. In this work, a stable symmetric sodium-ion battery based on the bipolar, active O3-type material, Na0.8Ni0.4Ti0.6O2, is developed. This bipolar material shows a typical O3-type layered structure, containing two electrochemically active transition metals with redox couples of Ni4+/Ni2+ and Ti4+/Ti3+, respectively. This Na0.8Ni0.4Ti0.6O2-based symmetric cell exhibits a high average voltage of 2.8 V, a reversible discharge capacity of 85 mA h g-1, 75% capacity retention after 150 cycles and good rate capability. This full symmetric cell will greatly contribute to the development of room-temperature sodium-ion batteries with a view towards safety, low cost and long life, and it will stimulate further research on symmetric cells using the same active materials as both cathode and anode.

    Original languageEnglish
    Pages (from-to)1237-1244
    Number of pages8
    JournalEnergy and Environmental Science
    Volume8
    Issue number4
    DOIs
    Publication statusPublished - 2015 Apr 1

    ASJC Scopus subject areas

    • Environmental Chemistry
    • Renewable Energy, Sustainability and the Environment
    • Nuclear Energy and Engineering
    • Pollution

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