High-Performance Supercapacitor Electrode Materials from Chitosan via Hydrothermal Carbonization and Potassium Hydroxide Activation

Linfeng Zhu, Feng Shen, Richard L. Smith, Xinhua Qi

Research output: Contribution to journalArticle

14 Citations (Scopus)

Abstract

Nitrogen-rich porous carbonaceous materials suitable for supercapacitor applications can be synthesized directly from chitosan using a hydrothermal treatment (250 °C, 14 h) that is followed by chemical activation of the carbonized solids with KOH (ca. 800 °C, 2 h). The synthesized chitosan-derived carbonaceous materials (CDCMs) had high specific surface area (ca. 2200 m2 g−1), large pore volume (ca. 1.36 cm3 g−1), and high nitrogen content (ca. 6.3 %). When a current density of 0.5 A g−1 was applied to CDCM-800 obtained at an activation temperature of 800 °C, specific capacitances of 231 and 305 F g−1 were achieved for 0.5 m K2SO4 and 6 m KOH aqueous electrolytes, respectively. Capacitances of 154 and 198 F g−1 were retained for the respective electrolytes at 20 Ag−1. CDCM-800 had an energy density of 8.5 Wh kg−1 corresponding to a specific power of 1 kW kg−1 at 20 A g−1 in 6 m KOH aqueous electrolytes. The prepared carbonaceous materials retained 99 % of their properties for over 3000 cycles at 1 A g−1 in 0.5 m K2SO4. The nitrogen-rich nanoporous carbonaceous materials have wide application in energy, electrical, chemical, analytic, separation, and catalysis.

Original languageEnglish
Pages (from-to)452-460
Number of pages9
JournalEnergy Technology
Volume5
Issue number3
DOIs
Publication statusPublished - 2017 Mar 1

Keywords

  • biomass
  • carbon
  • chitosan
  • hydrothermal carbonization
  • supercapacitors

ASJC Scopus subject areas

  • Energy(all)

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