Abstract
Nitrogen-rich porous carbonaceous materials suitable for supercapacitor applications can be synthesized directly from chitosan using a hydrothermal treatment (250 °C, 14 h) that is followed by chemical activation of the carbonized solids with KOH (ca. 800 °C, 2 h). The synthesized chitosan-derived carbonaceous materials (CDCMs) had high specific surface area (ca. 2200 m2 g−1), large pore volume (ca. 1.36 cm3 g−1), and high nitrogen content (ca. 6.3 %). When a current density of 0.5 A g−1 was applied to CDCM-800 obtained at an activation temperature of 800 °C, specific capacitances of 231 and 305 F g−1 were achieved for 0.5 m K2SO4 and 6 m KOH aqueous electrolytes, respectively. Capacitances of 154 and 198 F g−1 were retained for the respective electrolytes at 20 Ag−1. CDCM-800 had an energy density of 8.5 Wh kg−1 corresponding to a specific power of 1 kW kg−1 at 20 A g−1 in 6 m KOH aqueous electrolytes. The prepared carbonaceous materials retained 99 % of their properties for over 3000 cycles at 1 A g−1 in 0.5 m K2SO4. The nitrogen-rich nanoporous carbonaceous materials have wide application in energy, electrical, chemical, analytic, separation, and catalysis.
Original language | English |
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Pages (from-to) | 452-460 |
Number of pages | 9 |
Journal | Energy Technology |
Volume | 5 |
Issue number | 3 |
DOIs | |
Publication status | Published - 2017 Mar 1 |
Keywords
- biomass
- carbon
- chitosan
- hydrothermal carbonization
- supercapacitors
ASJC Scopus subject areas
- Energy(all)