High frequency ESR measurements on the spin crossover complex [Mn III(taa)]

S. Kimura; M. Hagiwara; Y. Narumi; M. Nakano; K. Kindo

doi:10.1088/1742-6596/200/2/022025

High frequency ESR measurements on the spin crossover complex [Mn ^III(taa)]

S. Kimura, M. Hagiwara, Y. Narumi, M. Nakano, K. Kindo

Materials Property Division

Research output: Contribution to journal › Conference article › peer-review

3 Citations (Scopus)

Abstract

We have performed ESR measurements on a single crystal of the spin crossover complex [Mn^III(taa)]. Symmetry lowering due to the Jahn-Teller effect in the High spin state of [Mn^III(taa)] is detected by the ESR measurements. From the analysis based on a spin Hamiltonian, we discuss the distortion in the molecular structure of [Mn^III(taa)].

Original language	English
Article number	022025
Journal	Journal of Physics: Conference Series
Volume	200
Issue number	SECTION 2
DOIs	https://doi.org/10.1088/1742-6596/200/2/022025
Publication status	Published - 2010

ASJC Scopus subject areas

Physics and Astronomy(all)

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abstract = "We have performed ESR measurements on a single crystal of the spin crossover complex [MnIII(taa)]. Symmetry lowering due to the Jahn-Teller effect in the High spin state of [MnIII(taa)] is detected by the ESR measurements. From the analysis based on a spin Hamiltonian, we discuss the distortion in the molecular structure of [MnIII(taa)].",

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T1 - High frequency ESR measurements on the spin crossover complex [Mn III(taa)]

AU - Kimura, S.

AU - Hagiwara, M.

AU - Narumi, Y.

AU - Nakano, M.

AU - Kindo, K.

PY - 2010

Y1 - 2010

N2 - We have performed ESR measurements on a single crystal of the spin crossover complex [MnIII(taa)]. Symmetry lowering due to the Jahn-Teller effect in the High spin state of [MnIII(taa)] is detected by the ESR measurements. From the analysis based on a spin Hamiltonian, we discuss the distortion in the molecular structure of [MnIII(taa)].

AB - We have performed ESR measurements on a single crystal of the spin crossover complex [MnIII(taa)]. Symmetry lowering due to the Jahn-Teller effect in the High spin state of [MnIII(taa)] is detected by the ESR measurements. From the analysis based on a spin Hamiltonian, we discuss the distortion in the molecular structure of [MnIII(taa)].

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U2 - 10.1088/1742-6596/200/2/022025

DO - 10.1088/1742-6596/200/2/022025

M3 - Conference article

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JO - Journal of Physics: Conference Series

JF - Journal of Physics: Conference Series

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