Hierarchical change of hydrogen bonds in phase transitions of molecular assemblages

Daisuke Ishii, Takeshi Yamada, Masaru Nakagawa, Hirohisa Yoshida, Tomokazu Iyoda

Research output: Contribution to conferencePaperpeer-review

Abstract

A hydrogen-bonded fibrous assemblage was formed from an amphoteric azopyridine carboxylic acid. In this report, we described the thermally induced change of hydrogen bonds among phase transitions of the fibrous assemblage. The fibrous assemblage made from an aqueous solution was composed of head-to-tail N⋯H-O strong hydrogen bonds and C-H⋯O weak hydrogen bonds cross-linked among the supramolecular polymers. The C-H⋯O weak hydrogen bonds in the fibrous assemblage were dissociated at 150 °C on 1st heating. On 1st cooling, C-H⋯O weak hydrogen bonds formed through re-crystallization at 17 °C were weaker than those in the original fibrous assemblage.

Original languageEnglish
Number of pages1
Publication statusPublished - 2005 Dec 1
Externally publishedYes
Event54th SPSJ Annual Meeting 2005 - Yokohama, Japan
Duration: 2005 May 252005 May 27

Other

Other54th SPSJ Annual Meeting 2005
CountryJapan
CityYokohama
Period05/5/2505/5/27

Keywords

  • DSC-FTIR
  • Hydrogen bond
  • Non-covalent bond
  • Phase transition
  • Self-assembly

ASJC Scopus subject areas

  • Engineering(all)

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