Hierarchical assembly of a phthalhydrazide-functionalized helicene

Takahiro Kaseyama, Seiichi Furumi, Xuan Zhang, Ken Tanaka, Masayuki Takeuchi

Research output: Contribution to journalArticlepeer-review

175 Citations (Scopus)

Abstract

(Figure Presented) High in fiber: 1D fibrous superstructures are formed by an enantiopure phthalhydrazide-functionalized helicene in nonpolar solvents. Trimeric disks are formed by hydrogen-bonding interactions of phthalhydrazide units that are longitudinally interlocked for optimal packing (see picture). The resulting supramolecular assemblies exhibited large circularly polarized luminescence in solution.

Original languageEnglish
Pages (from-to)3684-3687
Number of pages4
JournalAngewandte Chemie - International Edition
Volume50
Issue number16
DOIs
Publication statusPublished - 2011 Apr 11
Externally publishedYes

Keywords

  • Circular dichroism
  • Helicenes
  • Hydrogen bonding
  • Self-assembly
  • Supramolecular chemistry

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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