Hexagonal layered materials composed of [M2(O2CCF3)4] (M = Ru and Rh) donors and TCNQ acceptors

Hitoshi Miyasaka, Cristian S. Campos-Fernández, Rodolphe Clérac, Kim R. Dunbar

Research output: Contribution to journalArticle

176 Citations (Scopus)

Abstract

Delocalization throughout the extended layers of two-dimensional network polymers of the type [{M2(O2CCF3)4}2(TCNQ)·3(C7H8)]∞, which consist of Ru(II), Ru(II) and Rh(II), Rh(II) complexes coordinated to TCNQ molecules, is evident from the available structural (see picture for Ru analogue) and spectroscopic data. TCNQ = 7, 7, 8, 8-tetracyano-p-quinodimethane.

Original languageEnglish
Pages (from-to)3831-3835
Number of pages5
JournalAngewandte Chemie - International Edition
Volume39
Issue number21
DOIs
Publication statusPublished - 2000 Nov 3
Externally publishedYes

Keywords

  • Charge transfer
  • Delocalization
  • N ligands
  • Rhodium
  • Ruthenium

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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