Abstract
The heterometallic MnII4NiII2 title compound has been synthesized and characterized by X-ray crystallography. The compound consists of a Ni-Mn-Ni linear moiety, [{Ni-(μ-NO)3}2-Mn], linked by oximate bridges and three Mn(II) hfac terminal units attached by oximate oxygens in a di-μ-oxo fashion, forming a novel heterometallic cluster: Mn{Mn(hfac)2}3{Ni(pao)3}2 (1). Magnetic measurements reveal the antiferromagnetic nature of the oximate pathway between Mn(II) and Ni(II) metal ions, which imposes an unusual high-spin ground state (S = 8) for 1.
Original language | English |
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Pages (from-to) | 4501-4503 |
Number of pages | 3 |
Journal | Inorganic chemistry |
Volume | 42 |
Issue number | 15 |
Publication status | Published - 2003 Jul 28 |
Externally published | Yes |
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Inorganic Chemistry