Abstract
(Figure Presented) The dynamic dual chirality of D2-symmetric saddle-shaped porphyrin 1 decreases the stereochemical complexity of cocrystallization with racemic mandelic acid derivatives, such as BrMA, and allows spontaneous optical resolution (see picture). Each resulting cocrystal is porous and consists of one-handed double-helical porphyrin arrays in which chiral guests are enantioselectively included.
| Original language | English |
|---|---|
| Pages (from-to) | 3786-3790 |
| Number of pages | 5 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 45 |
| Issue number | 23 |
| DOIs | |
| Publication status | Published - 2006 Jun 2 |
Keywords
- Chiral recognition
- Chirality
- Host-guest systems
- Optical resolution
- Porphyrinoids
ASJC Scopus subject areas
- Catalysis
- Chemistry(all)
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Mizuno, Y., Alam, M. A., Tsuda, A., Kinbara, K., Yamaguchi, K., & Aida, T. (2006). Hermaphroditic chirality of a D2-symmetric saddle-shaped porphyrin in multicomponent spontaneous optical resolution: Inclusion cocrystals with double-helical porphyrin arrays. Angewandte Chemie - International Edition, 45(23), 3786-3790. https://doi.org/10.1002/anie.200503054