Abstract
(Figure Presented) The dynamic dual chirality of D2-symmetric saddle-shaped porphyrin 1 decreases the stereochemical complexity of cocrystallization with racemic mandelic acid derivatives, such as BrMA, and allows spontaneous optical resolution (see picture). Each resulting cocrystal is porous and consists of one-handed double-helical porphyrin arrays in which chiral guests are enantioselectively included.
Original language | English |
---|---|
Pages (from-to) | 3786-3790 |
Number of pages | 5 |
Journal | Angewandte Chemie - International Edition |
Volume | 45 |
Issue number | 23 |
DOIs | |
Publication status | Published - 2006 Jun 2 |
Keywords
- Chiral recognition
- Chirality
- Host-guest systems
- Optical resolution
- Porphyrinoids
ASJC Scopus subject areas
- Catalysis
- Chemistry(all)