Hermaphroditic chirality of a D2-symmetric saddle-shaped porphyrin in multicomponent spontaneous optical resolution: Inclusion cocrystals with double-helical porphyrin arrays

Yukitami Mizuno; Md Akhtarul Alam; Akihiko Tsuda; Kazushi Kinbara; Kentaro Yamaguchi; Takuzo Aida

doi:10.1002/anie.200503054

Hermaphroditic chirality of a D₂-symmetric saddle-shaped porphyrin in multicomponent spontaneous optical resolution: Inclusion cocrystals with double-helical porphyrin arrays

Yukitami Mizuno, Md Akhtarul Alam, Akihiko Tsuda, Kazushi Kinbara, Kentaro Yamaguchi, Takuzo Aida

Institute of Multidisciplinary Research for Advanced Materials (IMRAM)

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

(Figure Presented) The dynamic dual chirality of D₂-symmetric saddle-shaped porphyrin 1 decreases the stereochemical complexity of cocrystallization with racemic mandelic acid derivatives, such as BrMA, and allows spontaneous optical resolution (see picture). Each resulting cocrystal is porous and consists of one-handed double-helical porphyrin arrays in which chiral guests are enantioselectively included.

Original language	English
Pages (from-to)	3786-3790
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	45
Issue number	23
DOIs	https://doi.org/10.1002/anie.200503054
Publication status	Published - 2006 Jun 2

Keywords

Chiral recognition
Chirality
Host-guest systems
Optical resolution
Porphyrinoids

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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Hermaphroditic chirality of a D₂-symmetric saddle-shaped porphyrin in multicomponent spontaneous optical resolution : Inclusion cocrystals with double-helical porphyrin arrays. / Mizuno, Yukitami; Alam, Md Akhtarul; Tsuda, Akihiko; Kinbara, Kazushi; Yamaguchi, Kentaro; Aida, Takuzo.

In: Angewandte Chemie - International Edition, Vol. 45, No. 23, 02.06.2006, p. 3786-3790.

Research output: Contribution to journal › Article › peer-review

Mizuno, Yukitami ; Alam, Md Akhtarul ; Tsuda, Akihiko ; Kinbara, Kazushi ; Yamaguchi, Kentaro ; Aida, Takuzo. / Hermaphroditic chirality of a D₂-symmetric saddle-shaped porphyrin in multicomponent spontaneous optical resolution : Inclusion cocrystals with double-helical porphyrin arrays. In: Angewandte Chemie - International Edition. 2006 ; Vol. 45, No. 23. pp. 3786-3790.

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