Heck reactions in a non-aqueous ionic liquid using silica supported palladium complex catalysts

Keisuke Okubo, Masayuki Shirai, Chiaki Yokoyama

Research output: Contribution to journalArticlepeer-review

76 Citations (Scopus)

Abstract

The Heck reaction of iodobenzene and 4-methyl-iodobenzene with olefins using silica-supported palladium complex catalysts was conducted in 1-butyl-3-methylimidazolium hexafluorophosphate ([bmim]PF6), exhibiting higher activities than in DMF in addition to easy product isolation and catalyst recycling.

Original languageEnglish
Pages (from-to)7115-7118
Number of pages4
JournalTetrahedron Letters
Volume43
Issue number39
DOIs
Publication statusPublished - 2002 Sep 23

Keywords

  • Heck reaction
  • Ionic liquid
  • Supported palladium catalyst

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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