Halogen substituted tetraselenafulvalene derivatives

K. Takimiya, Y. Kataoka, A. Morikami, Y. Aso, T. Otsubo

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

The synthesis and electrochemical properties of di- and tetra-halogenated tetraselenafulvalene (TSF) derivatives are presented. The synthetic method involves an efficient formation of halogen substituted 1,3-diselenole-2-selones from readily available starting materials. Electrochemical crystallization afforded several radical cation salts, and, of them, the ClO4 salt of the dimethyl-dibromo-TSF showed a high conductivity of 400 S cm-1 at room temperature and retained metallic down to ca. 90 K.

Original languageEnglish
Pages (from-to)875-876
Number of pages2
JournalSynthetic Metals
Volume120
Issue number1-3
DOIs
Publication statusPublished - 2001 Mar 15
Externally publishedYes

Keywords

  • Electrocrystallization
  • Heterocycle synthesis
  • Organic conductor
  • Radical cation salts

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry

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