Halogen-bridged PtII/PtIV mixed-valence ladder compounds

Daisuke Kawakami, Masahiro Yamashita, Satoshi Matsunaga, Shinya Takaishi, Takashi Kajiwara, Hitoshi Miyasaka, Ken Ichi Sugiura, Hiroyuki Matsuzaki, Hiroshi Okamoto, Yusuke Wakabayashi, Hiroshi Sawa

Research output: Contribution to journalArticlepeer-review

23 Citations (Scopus)

Abstract

Chutes and ... Ladders in coordination networks represent a boundary between 1D and 2D systems. Halogen-bridged PtII/PtIV mixed-valence ladder compounds have been synthesized for the first time. In these compounds, the band gap is controlled by changing the bridging halide ions. Moreover, by changing counteranions, the charge arrangements of the ladder compounds can be controlled. (Figure Presented).

Original languageEnglish
Pages (from-to)7214-7217
Number of pages4
JournalAngewandte Chemie - International Edition
Volume45
Issue number43
DOIs
Publication statusPublished - 2006 Nov 3

Keywords

  • Charge transfer
  • Coordination modes
  • Ladder polymers
  • Mixed-valent compounds
  • Valence structures

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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