Halogen-bridged PtII/PtIV mixed-valence ladder compounds

Daisuke Kawakami; Masahiro Yamashita; Satoshi Matsunaga; Shinya Takaishi; Takashi Kajiwara; Hitoshi Miyasaka; Ken Ichi Sugiura; Hiroyuki Matsuzaki; Hiroshi Okamoto; Yusuke Wakabayashi; Hiroshi Sawa

doi:10.1002/anie.200602987

Halogen-bridged Pt^II/Pt^IV mixed-valence ladder compounds

Daisuke Kawakami, Masahiro Yamashita, Satoshi Matsunaga, Shinya Takaishi, Takashi Kajiwara, Hitoshi Miyasaka, Ken Ichi Sugiura, Hiroyuki Matsuzaki, Hiroshi Okamoto, Yusuke Wakabayashi, Hiroshi Sawa

Research output: Contribution to journal › Article › peer-review

31 Citations (Scopus)

Abstract

Chutes and ... Ladders in coordination networks represent a boundary between 1D and 2D systems. Halogen-bridged Pt^II/Pt^IV mixed-valence ladder compounds have been synthesized for the first time. In these compounds, the band gap is controlled by changing the bridging halide ions. Moreover, by changing counteranions, the charge arrangements of the ladder compounds can be controlled. (Figure Presented).

Original language	English
Pages (from-to)	7214-7217
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	45
Issue number	43
DOIs	https://doi.org/10.1002/anie.200602987
Publication status	Published - 2006 Nov 3

Keywords

Charge transfer
Coordination modes
Ladder polymers
Mixed-valent compounds
Valence structures

ASJC Scopus subject areas

Catalysis
Chemistry(all)

Access to Document

10.1002/anie.200602987

Cite this

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title = "Halogen-bridged PtII/PtIV mixed-valence ladder compounds",

abstract = "Chutes and ... Ladders in coordination networks represent a boundary between 1D and 2D systems. Halogen-bridged PtII/PtIV mixed-valence ladder compounds have been synthesized for the first time. In these compounds, the band gap is controlled by changing the bridging halide ions. Moreover, by changing counteranions, the charge arrangements of the ladder compounds can be controlled. (Figure Presented).",

keywords = "Charge transfer, Coordination modes, Ladder polymers, Mixed-valent compounds, Valence structures",

author = "Daisuke Kawakami and Masahiro Yamashita and Satoshi Matsunaga and Shinya Takaishi and Takashi Kajiwara and Hitoshi Miyasaka and Sugiura, {Ken Ichi} and Hiroyuki Matsuzaki and Hiroshi Okamoto and Yusuke Wakabayashi and Hiroshi Sawa",

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T1 - Halogen-bridged PtII/PtIV mixed-valence ladder compounds

AU - Kawakami, Daisuke

AU - Yamashita, Masahiro

AU - Matsunaga, Satoshi

AU - Takaishi, Shinya

AU - Kajiwara, Takashi

AU - Miyasaka, Hitoshi

AU - Sugiura, Ken Ichi

AU - Matsuzaki, Hiroyuki

AU - Okamoto, Hiroshi

AU - Wakabayashi, Yusuke

AU - Sawa, Hiroshi

PY - 2006/11/3

Y1 - 2006/11/3

N2 - Chutes and ... Ladders in coordination networks represent a boundary between 1D and 2D systems. Halogen-bridged PtII/PtIV mixed-valence ladder compounds have been synthesized for the first time. In these compounds, the band gap is controlled by changing the bridging halide ions. Moreover, by changing counteranions, the charge arrangements of the ladder compounds can be controlled. (Figure Presented).

AB - Chutes and ... Ladders in coordination networks represent a boundary between 1D and 2D systems. Halogen-bridged PtII/PtIV mixed-valence ladder compounds have been synthesized for the first time. In these compounds, the band gap is controlled by changing the bridging halide ions. Moreover, by changing counteranions, the charge arrangements of the ladder compounds can be controlled. (Figure Presented).

KW - Charge transfer

KW - Coordination modes

KW - Ladder polymers

KW - Mixed-valent compounds

KW - Valence structures

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