Group theoretical classification of electronic states in mixed-valence complexes

Veaceslav P. Coropceanu, Kosmas Prassides

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

A group theoretical method is developed to treat the ground and excited electronic states of multielectronic polynuclear mixed-valence systems of the general form dn-...-dn-dn+1-...-dn+1 and fn-...-fn-fn+1-...-fn+1. Effects arising from electronic degeneracy, spin-orbit interactions and reduced site symmetry are explicitly taken into account. The versatility of the technique is demonstrated by applying it to a series of trimeric mixed-valence clusters.

Original languageEnglish
Pages (from-to)53-59
Number of pages7
JournalChemical Physics Letters
Volume289
Issue number1-2
DOIs
Publication statusPublished - 1998 Jun 5

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

Fingerprint Dive into the research topics of 'Group theoretical classification of electronic states in mixed-valence complexes'. Together they form a unique fingerprint.

  • Cite this