Group 6 metal complexes with a hemilabile tridentate xantsil ligand and facile insertion of tBuCN into a W-Si bond [xantsil = (9,9-dimethylxanthene-4,5-diyl)bis(dimethylsilyl)]

Rockshana Begum; Takashi Komuro; Hiromi Tobita

doi:10.1039/b512759a

Group 6 metal complexes with a hemilabile tridentate xantsil ligand and facile insertion of ^tBuCN into a W-Si bond [xantsil = (9,9-dimethylxanthene-4,5-diyl)bis(dimethylsilyl)]

Rockshana Begum, Takashi Komuro, Hiromi Tobita

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

The synthesis and characterization of tungsten and molybdenum complexes of the xanthene-based bis(silyl) ligand (xantsil) with a κ³(Si,Si, O) coordination mode are reported, where an insertion of ^tBuCN into a tungsten-silicon bond leads to formation of an η²-iminoacyl complex.

Original language	English
Pages (from-to)	432-433
Number of pages	2
Journal	Chemical Communications
Issue number	4
DOIs	https://doi.org/10.1039/b512759a
Publication status	Published - 2006 Apr 6

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Access to Document

10.1039/b512759a

Cite this

@article{9488a51d74274042a96554e12ee91e49,

title = "Group 6 metal complexes with a hemilabile tridentate xantsil ligand and facile insertion of tBuCN into a W-Si bond [xantsil = (9,9-dimethylxanthene-4,5-diyl)bis(dimethylsilyl)]",

abstract = "The synthesis and characterization of tungsten and molybdenum complexes of the xanthene-based bis(silyl) ligand (xantsil) with a κ3(Si,Si, O) coordination mode are reported, where an insertion of tBuCN into a tungsten-silicon bond leads to formation of an η2-iminoacyl complex.",

author = "Rockshana Begum and Takashi Komuro and Hiromi Tobita",

year = "2006",

month = apr,

day = "6",

doi = "10.1039/b512759a",

language = "English",

pages = "432--433",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "4",

}

TY - JOUR

T1 - Group 6 metal complexes with a hemilabile tridentate xantsil ligand and facile insertion of tBuCN into a W-Si bond [xantsil = (9,9-dimethylxanthene-4,5-diyl)bis(dimethylsilyl)]

AU - Begum, Rockshana

AU - Komuro, Takashi

AU - Tobita, Hiromi

PY - 2006/4/6

Y1 - 2006/4/6

N2 - The synthesis and characterization of tungsten and molybdenum complexes of the xanthene-based bis(silyl) ligand (xantsil) with a κ3(Si,Si, O) coordination mode are reported, where an insertion of tBuCN into a tungsten-silicon bond leads to formation of an η2-iminoacyl complex.

AB - The synthesis and characterization of tungsten and molybdenum complexes of the xanthene-based bis(silyl) ligand (xantsil) with a κ3(Si,Si, O) coordination mode are reported, where an insertion of tBuCN into a tungsten-silicon bond leads to formation of an η2-iminoacyl complex.

UR - http://www.scopus.com/inward/record.url?scp=33645459912&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=33645459912&partnerID=8YFLogxK

U2 - 10.1039/b512759a

DO - 10.1039/b512759a

M3 - Article

AN - SCOPUS:33645459912

SN - 1359-7345

SP - 432

EP - 433

JO - Chemical Communications

JF - Chemical Communications

IS - 4

ER -

Group 6 metal complexes with a hemilabile tridentate xantsil ligand and facile insertion of ^tBuCN into a W-Si bond [xantsil = (9,9-dimethylxanthene-4,5-diyl)bis(dimethylsilyl)]

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this