Gold-catalysed alkenyl- and arylsilylation reactions forming 1-silaindenes

Takanori Matsuda, Yoshiyuki Yamaguchi, Masanori Shigeno, Shinya Sato, Masahiro Murakami

Research output: Contribution to journalArticle

24 Citations (Scopus)

Abstract

In the presence of gold(i)-phosphine catalysts, alkenyl- and arylsilanes undergo intramolecular cyclisation reactions onto appendant alkyne moieties to afford 1-silaindene derivatives. The reaction pathways vary depending on the substituent on silicon.

Original languageEnglish
Pages (from-to)8697-8699
Number of pages3
JournalChemical Communications
Volume47
Issue number30
DOIs
Publication statusPublished - 2011 Aug 14
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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