Glycerol Oxidation Catalyzed by High-valency Ruthenium Species at Electrochemical Interfaces

Hiro Tabata, Shintaro Kato, Shingi Yamaguchi, Takashi Harada, Kazuyuki Iwase, Kazuhide Kamiya, Shuji Nakanishi

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

Herein we report high-valency ruthenium (Ru) species as a new class of electrocatalyst for glycerol oxidation. In this study, Ru-modified covalent triazine framework (Ru-CTF) and ruthenium oxide supported on carbon (RuO2/C) were used as model materials with high-valency Ru species. The results of this work show that the deep oxidation reactions of glycerol involving C-C bond cleavage can be effectively suppressed by increasing the glycerol concentration relative to the number of active Ru atoms for both catalysts.

Original languageEnglish
Article numberCL-200056
Pages (from-to)513-516
Number of pages4
JournalChemistry Letters
Volume49
Issue number5
DOIs
Publication statusPublished - 2020 May

Keywords

  • Electrocatalyst
  • Glycerol
  • Ruthenium

ASJC Scopus subject areas

  • Chemistry(all)

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    Tabata, H., Kato, S., Yamaguchi, S., Harada, T., Iwase, K., Kamiya, K., & Nakanishi, S. (2020). Glycerol Oxidation Catalyzed by High-valency Ruthenium Species at Electrochemical Interfaces. Chemistry Letters, 49(5), 513-516. [CL-200056]. https://doi.org/10.1246/cl.200056