Gigantic optical nonlinearity in one-dimensional Mott-Hubbard insulators

H. Kishida, H. Matsuzaki, H. Okamoto, T. Manabe, M. Yamashita, Y. Taguchi, Y. Tokura

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294 Citations (Scopus)

Abstract

The realization of all-optical switching, modulating and computing devices is an important goal in modern optical technology. Nonlinear optical materials with large third-order nonlinear susceptibilities (χ((3))) are indispensable for such devices, because the magnitude of this quantity dominates the device performance. A key strategy in the development of new materials with large nonlinear susceptibilities is the exploration of quasi- one-dimensional systems, or 'quantum wires' - the quantum confinement of electron-hole motion in one-dimensional space can enhance χ((3)). Two types of chemically synthesized-quantum wires have been extensively studied: the band insulators of silicon polymers, and Peierls insulators of π-conjugated polymers and platinum halides. In these systems, χ((3)) values of 10-12 to 10-7 e.s.u. (electrostatic system of units) have been reported. Here we demonstrate an anomalous enhancement of the third-order nonlinear susceptibility in a different category of quantum wires: one-dimensional Mott insulators of 3d transition-metal oxides and halides. By analysing the electroreflectance spectra of these compounds, we measure χ((3)) values in the range 10-8 to 10-5 e.s.u. The anomalous enhancement results from a large dipole-moment between the lowest two excited states of these systems.

Original languageEnglish
Pages (from-to)929-930
Number of pages2
JournalNature
Volume405
Issue number6789
DOIs
Publication statusPublished - 2000 Jun 22
Externally publishedYes

ASJC Scopus subject areas

  • General

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    Kishida, H., Matsuzaki, H., Okamoto, H., Manabe, T., Yamashita, M., Taguchi, Y., & Tokura, Y. (2000). Gigantic optical nonlinearity in one-dimensional Mott-Hubbard insulators. Nature, 405(6789), 929-930. https://doi.org/10.1038/35016036