Generation of arylzinc reagents through an iodine-zinc exchange reaction promoted by a non-metallic organic superbase

Hiroshi Naka, Keisuke Ito, Masahiro Ueno, Koji Kobayashi, Yoshinori Kondo

Research output: Contribution to journalArticlepeer-review

5 Citations (Scopus)

Abstract

Functionalized aryl and heteroaryl zinc reagents were prepared from aryl iodides and diethylzinc through t-Bu-P4 base-promoted iodine-zinc exchange reactions. The scope and limitations of this protocol, and several applications for the synthesis of oligoaryls and fused aromatics, are presented.

Original languageEnglish
Pages (from-to)1700-1706
Number of pages7
JournalNew Journal of Chemistry
Volume34
Issue number8
DOIs
Publication statusPublished - 2010 Aug 1

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Materials Chemistry

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