Generation of arylzinc reagents through an iodine-zinc exchange reaction promoted by a non-metallic organic superbase

Hiroshi Naka; Keisuke Ito; Masahiro Ueno; Koji Kobayashi; Yoshinori Kondo

doi:10.1039/c0nj00202j

Generation of arylzinc reagents through an iodine-zinc exchange reaction promoted by a non-metallic organic superbase

Hiroshi Naka, Keisuke Ito, Masahiro Ueno, Koji Kobayashi, Yoshinori Kondo

PHA - Molecular Pharmaceutical Science

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

Functionalized aryl and heteroaryl zinc reagents were prepared from aryl iodides and diethylzinc through t-Bu-P₄ base-promoted iodine-zinc exchange reactions. The scope and limitations of this protocol, and several applications for the synthesis of oligoaryls and fused aromatics, are presented.

Original language	English
Pages (from-to)	1700-1706
Number of pages	7
Journal	New Journal of Chemistry
Volume	34
Issue number	8
DOIs	https://doi.org/10.1039/c0nj00202j
Publication status	Published - 2010 Aug 1

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Materials Chemistry

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abstract = "Functionalized aryl and heteroaryl zinc reagents were prepared from aryl iodides and diethylzinc through t-Bu-P4 base-promoted iodine-zinc exchange reactions. The scope and limitations of this protocol, and several applications for the synthesis of oligoaryls and fused aromatics, are presented.",

author = "Hiroshi Naka and Keisuke Ito and Masahiro Ueno and Koji Kobayashi and Yoshinori Kondo",

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AU - Naka, Hiroshi

AU - Ito, Keisuke

AU - Ueno, Masahiro

AU - Kobayashi, Koji

AU - Kondo, Yoshinori

PY - 2010/8/1

Y1 - 2010/8/1

N2 - Functionalized aryl and heteroaryl zinc reagents were prepared from aryl iodides and diethylzinc through t-Bu-P4 base-promoted iodine-zinc exchange reactions. The scope and limitations of this protocol, and several applications for the synthesis of oligoaryls and fused aromatics, are presented.

AB - Functionalized aryl and heteroaryl zinc reagents were prepared from aryl iodides and diethylzinc through t-Bu-P4 base-promoted iodine-zinc exchange reactions. The scope and limitations of this protocol, and several applications for the synthesis of oligoaryls and fused aromatics, are presented.

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Generation of arylzinc reagents through an iodine-zinc exchange reaction promoted by a non-metallic organic superbase

Abstract

ASJC Scopus subject areas

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