Abstract

A new method to synthesize fullerene and sulfur compounds, C60S16 and C70S16 compounds of about 1 mm length, has been developed. The C60S16 crystal is a C-centered monoclinic structure of a = 2.0874(1)nm, b = 2.1139(1)nm, c = 1.05690(6)nm and β = 111.9 degree. The C70S16 compound has a primitive monoclinic structure of a = 1.5271(2) nm, b = 1.49971(7) nm, c = 2.18024(9) nm and β = 109.791(1)degree. The crystalline structure of these compounds is constructed by fullerene and S8-rings. A very small amount of charge-transfer between fullerenes and sulfur rings are expected by first-principle calculation.

Original languageEnglish
Pages (from-to)1530-1532
Number of pages3
JournalMaterials Transactions
Volume43
Issue number7
DOIs
Publication statusPublished - 2002 Jul

Keywords

  • Charge transfer
  • Crystal structures
  • Fullerene
  • Sulfur

ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering

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  • Cite this

    Takahashi, H., Matsubara, E., Belosludov, R. V., Matsubara, S., Sato, N., Muramatsu, A., Kawazoe, Y., & Tohji, K. (2002). Fullerene and sulfur compounds. Materials Transactions, 43(7), 1530-1532. https://doi.org/10.2320/matertrans.43.1530