Fourteen-electron bis(dialkylsilylene)palladium and twelve-electron bis(dialkylsilyl)palladium complexes

Chieko Watanabe; Takeaki Iwamoto; Chizuko Kabuto; Mitsuo Kira

doi:10.1002/anie.200705954

Fourteen-electron bis(dialkylsilylene)palladium and twelve-electron bis(dialkylsilyl)palladium complexes

Chieko Watanabe, Takeaki Iwamoto, Chizuko Kabuto, Mitsuo Kira

SCI - Chemistry

Research output: Contribution to journal › Article › peer-review

37 Citations (Scopus)

Abstract

(Figure Presented) Silylene Complexes Hydrogens make a difference: The first 14-electron bis(silylene)palladium (A) and 12-electron bis(silyl)palladium complexes (B) are synthesized from a stable dialkylsilylene (see picture; gold: Pd; dark blue: Si; light blue: C; magenta: H). The remarkable difference between the L-M-L angles of these two complexes is rationalized by applying the Walsh diagram.

Original language	English
Pages (from-to)	5386-5389
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	47
Issue number	29
DOIs	https://doi.org/10.1002/anie.200705954
Publication status	Published - 2008 Jul 7

Keywords

Agostic interactions
Heterometallic complexes
Hydrogenation
Palladium
Silicon

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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10.1002/anie.200705954

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title = "Fourteen-electron bis(dialkylsilylene)palladium and twelve-electron bis(dialkylsilyl)palladium complexes",

abstract = "(Figure Presented) Silylene Complexes Hydrogens make a difference: The first 14-electron bis(silylene)palladium (A) and 12-electron bis(silyl)palladium complexes (B) are synthesized from a stable dialkylsilylene (see picture; gold: Pd; dark blue: Si; light blue: C; magenta: H). The remarkable difference between the L-M-L angles of these two complexes is rationalized by applying the Walsh diagram.",

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T1 - Fourteen-electron bis(dialkylsilylene)palladium and twelve-electron bis(dialkylsilyl)palladium complexes

AU - Watanabe, Chieko

AU - Iwamoto, Takeaki

AU - Kabuto, Chizuko

AU - Kira, Mitsuo

PY - 2008/7/7

Y1 - 2008/7/7

N2 - (Figure Presented) Silylene Complexes Hydrogens make a difference: The first 14-electron bis(silylene)palladium (A) and 12-electron bis(silyl)palladium complexes (B) are synthesized from a stable dialkylsilylene (see picture; gold: Pd; dark blue: Si; light blue: C; magenta: H). The remarkable difference between the L-M-L angles of these two complexes is rationalized by applying the Walsh diagram.

AB - (Figure Presented) Silylene Complexes Hydrogens make a difference: The first 14-electron bis(silylene)palladium (A) and 12-electron bis(silyl)palladium complexes (B) are synthesized from a stable dialkylsilylene (see picture; gold: Pd; dark blue: Si; light blue: C; magenta: H). The remarkable difference between the L-M-L angles of these two complexes is rationalized by applying the Walsh diagram.

KW - Agostic interactions

KW - Heterometallic complexes

KW - Hydrogenation

KW - Palladium

KW - Silicon

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