Formation of coordination polymer glass by mechanical milling: Dependence on metal ions and molecular doping for H+ conductivity

Yuki Ohara; Akira Hinokimoto; Wenqian Chen; Takashi Kitao; Yusuke Nishiyama; You Lee Hong; Susumu Kitagawa; Satoshi Horike

doi:10.1039/c8cc02399a

Formation of coordination polymer glass by mechanical milling: Dependence on metal ions and molecular doping for H⁺ conductivity

Yuki Ohara, Akira Hinokimoto, Wenqian Chen, Takashi Kitao, Yusuke Nishiyama, You Lee Hong, Susumu Kitagawa, Satoshi Horike

Advanced Institute for Materials Research (AIMR)

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

Four isostructural coordination polymer crystals having different metal ions were synthesized and studied for ball milling-induced glass formation. Distinct glass formation was discussed from crystal structures. Doping of molecules for CP glass during the milling was demonstrated, and it resulted in tunable glass properties (T_g and T_c) and enhancement of anhydrous H⁺ conductivity.

Original language	English
Pages (from-to)	6859-6862
Number of pages	4
Journal	Chemical Communications
Volume	54
Issue number	50
DOIs	https://doi.org/10.1039/c8cc02399a
Publication status	Published - 2018 Jan 1

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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Formation of coordination polymer glass by mechanical milling : Dependence on metal ions and molecular doping for H⁺ conductivity. / Ohara, Yuki; Hinokimoto, Akira; Chen, Wenqian; Kitao, Takashi; Nishiyama, Yusuke; Hong, You Lee; Kitagawa, Susumu; Horike, Satoshi.

In: Chemical Communications, Vol. 54, No. 50, 01.01.2018, p. 6859-6862.

Research output: Contribution to journal › Article › peer-review

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