Formation of coordination polymer glass by mechanical milling: Dependence on metal ions and molecular doping for H+ conductivity

Yuki Ohara; Akira Hinokimoto; Wenqian Chen; Takashi Kitao; Yusuke Nishiyama; You Lee Hong; Susumu Kitagawa; Satoshi Horike

doi:10.1039/c8cc02399a

Formation of coordination polymer glass by mechanical milling: Dependence on metal ions and molecular doping for H⁺ conductivity

Yuki Ohara, Akira Hinokimoto, Wenqian Chen, Takashi Kitao, Yusuke Nishiyama, You Lee Hong, Susumu Kitagawa, Satoshi Horike

Advanced Institute for Materials Research (AIMR)

Research output: Contribution to journal › Article › peer-review

22 Citations (Scopus)

Abstract

Four isostructural coordination polymer crystals having different metal ions were synthesized and studied for ball milling-induced glass formation. Distinct glass formation was discussed from crystal structures. Doping of molecules for CP glass during the milling was demonstrated, and it resulted in tunable glass properties (T_g and T_c) and enhancement of anhydrous H⁺ conductivity.

Original language	English
Pages (from-to)	6859-6862
Number of pages	4
Journal	Chemical Communications
Volume	54
Issue number	50
DOIs	https://doi.org/10.1039/c8cc02399a
Publication status	Published - 2018 Jan 1

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c8cc02399a

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Formation of coordination polymer glass by mechanical milling : Dependence on metal ions and molecular doping for H⁺ conductivity. / Ohara, Yuki; Hinokimoto, Akira; Chen, Wenqian; Kitao, Takashi; Nishiyama, Yusuke; Hong, You Lee; Kitagawa, Susumu; Horike, Satoshi.

In: Chemical Communications, Vol. 54, No. 50, 01.01.2018, p. 6859-6862.

Research output: Contribution to journal › Article › peer-review

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AU - Ohara, Yuki

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AU - Nishiyama, Yusuke

AU - Hong, You Lee

AU - Kitagawa, Susumu

AU - Horike, Satoshi

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AB - Four isostructural coordination polymer crystals having different metal ions were synthesized and studied for ball milling-induced glass formation. Distinct glass formation was discussed from crystal structures. Doping of molecules for CP glass during the milling was demonstrated, and it resulted in tunable glass properties (Tg and Tc) and enhancement of anhydrous H+ conductivity.

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Formation of coordination polymer glass by mechanical milling: Dependence on metal ions and molecular doping for H⁺ conductivity

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