Formation of coordination polymer glass by mechanical milling: Dependence on metal ions and molecular doping for H+ conductivity

Yuki Ohara, Akira Hinokimoto, Wenqian Chen, Takashi Kitao, Yusuke Nishiyama, You Lee Hong, Susumu Kitagawa, Satoshi Horike

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

Four isostructural coordination polymer crystals having different metal ions were synthesized and studied for ball milling-induced glass formation. Distinct glass formation was discussed from crystal structures. Doping of molecules for CP glass during the milling was demonstrated, and it resulted in tunable glass properties (Tg and Tc) and enhancement of anhydrous H+ conductivity.

Original languageEnglish
Pages (from-to)6859-6862
Number of pages4
JournalChemical Communications
Volume54
Issue number50
DOIs
Publication statusPublished - 2018 Jan 1

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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    Ohara, Y., Hinokimoto, A., Chen, W., Kitao, T., Nishiyama, Y., Hong, Y. L., Kitagawa, S., & Horike, S. (2018). Formation of coordination polymer glass by mechanical milling: Dependence on metal ions and molecular doping for H+ conductivity. Chemical Communications, 54(50), 6859-6862. https://doi.org/10.1039/c8cc02399a