Formation of amorphous Pt oxides: Characterization and their catalysis

Satoshi Kameoka, Masahiko Shimoda, Yoshitaka Matsushita, Yoshiyuki Yamashita, Yoshio Katsuya, Masahiko Tanaka, An Pang Tsai

    Research output: Contribution to journalArticlepeer-review

    1 Citation (Scopus)

    Abstract

    Amorphous Pt oxides (am-PtOx) were formed by the leaching of copper from a Cu3Pt alloy in concentrated HNO3 at 323K for 12 h. The resulting am-PtOx was characterized using synchrotron X-ray powder diffraction, hard X-ray photoelectron spectroscopy, thermal analysis (TGDTA, TPD) and the BET method. This material had a high specific surface area with micropores (61.7m2/g) and decomposed to form Pt and O2 at approximately 720 K. The catalytic performance of the am-PtOx during CO oxidation was superior to that of a conventional Pt black catalyst. This study demonstrated a novel method of preparing am-PtOx with applications as a catalyst.

    Original languageEnglish
    Pages (from-to)490-494
    Number of pages5
    JournalMaterials Transactions
    Volume56
    Issue number4
    DOIs
    Publication statusPublished - 2015

    Keywords

    • Amorphous platinum (Pt) oxides
    • Carbon monoxide (CO) oxidation
    • Catalytic material
    • Cu<inf>3</inf>Pt
    • Leaching
    • PtO<inf>x</inf>

    ASJC Scopus subject areas

    • Materials Science(all)
    • Condensed Matter Physics
    • Mechanics of Materials
    • Mechanical Engineering

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