Formation of a diaminoalkyne derivative by dialumane-mediated homocoupling of t-butyl isocyanide

Koichi Nagata, Tomohiro Agou, Takahiro Sasamori, Norihiro Tokitoh

Research output: Contribution to journalArticlepeer-review

7 Citations (Scopus)

Abstract

Treatment of a stable dialumane derivative with an excess of t-butyl isocyanide resulted in the homocoupling of the isocyanide to form a diaminoalkyne skeleton. A one-to-one insertion product of the isocyanide with the dialumane should be the intermediate for the generation of the diaminoalkyne derivative.

Original languageEnglish
Pages (from-to)1610-1612
Number of pages3
JournalChemistry Letters
Volume44
Issue number11
DOIs
Publication statusPublished - 2015 Jan 1
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)

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