Formation of a c(2 × 2) overlayer of nitrogen on Pd(100) by NO + CO reaction or NO + H2 reaction

Taro Yamada; Iwao Matsuo; Junji Nakamura; Maosong Xie; Hideki Hirano; Yoshio Matsumoto; Ken Ichi Tanaka

doi:10.1016/0039-6028(90)90199-I

Formation of a c(2 × 2) overlayer of nitrogen on Pd(100) by NO + CO reaction or NO + H₂ reaction

Taro Yamada, Iwao Matsuo, Junji Nakamura, Maosong Xie, Hideki Hirano, Yoshio Matsumoto, Ken Ichi Tanaka

Research output: Contribution to journal › Article › peer-review

20 Citations (Scopus)

Abstract

A nitrogen overlayer (N(a)) was synthesized on Pd(100) by catalytic reduction of NO by CO or H₂ in the total pressure range of 10^-7-10¹ Torr at crystal temperatures higher than 500 K. The process of the formation of N(a) was monitored by AES, LEED, HREELS and TDS. N(a) formed a c(2 × 2) superlattice, and desorbed at 600-700 K. N(a) was hydrogenated by gas-phase H₂. HREELS revealed the reversible formation of NH_x(a) species on the surface.

Original language	English
Pages (from-to)	304-314
Number of pages	11
Journal	Surface Science
Volume	231
Issue number	3
DOIs	https://doi.org/10.1016/0039-6028(90)90199-I
Publication status	Published - 1990 May 3
Externally published	Yes

ASJC Scopus subject areas

Condensed Matter Physics
Surfaces and Interfaces
Surfaces, Coatings and Films
Materials Chemistry

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10.1016/0039-6028(90)90199-I

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title = "Formation of a c(2 × 2) overlayer of nitrogen on Pd(100) by NO + CO reaction or NO + H2 reaction",

abstract = "A nitrogen overlayer (N(a)) was synthesized on Pd(100) by catalytic reduction of NO by CO or H2 in the total pressure range of 10-7-101 Torr at crystal temperatures higher than 500 K. The process of the formation of N(a) was monitored by AES, LEED, HREELS and TDS. N(a) formed a c(2 × 2) superlattice, and desorbed at 600-700 K. N(a) was hydrogenated by gas-phase H2. HREELS revealed the reversible formation of NHx(a) species on the surface.",

author = "Taro Yamada and Iwao Matsuo and Junji Nakamura and Maosong Xie and Hideki Hirano and Yoshio Matsumoto and Tanaka, {Ken Ichi}",

note = "Funding Information: This work was promoted by a Grant in Aid No. 63609005f or Scientific Research on Priority Area of the Ministry of Education of Japan. The authors appreciate the financial supports by Yamada Science Foundation, Murata Science Foundation and CASIO Science Promotion Fund. Copyright: Copyright 2014 Elsevier B.V., All rights reserved.",

year = "1990",

month = may,

day = "3",

doi = "10.1016/0039-6028(90)90199-I",

language = "English",

volume = "231",

pages = "304--314",

journal = "Surface Science",

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TY - JOUR

T1 - Formation of a c(2 × 2) overlayer of nitrogen on Pd(100) by NO + CO reaction or NO + H2 reaction

AU - Yamada, Taro

AU - Matsuo, Iwao

AU - Nakamura, Junji

AU - Xie, Maosong

AU - Hirano, Hideki

AU - Matsumoto, Yoshio

AU - Tanaka, Ken Ichi

N1 - Funding Information: This work was promoted by a Grant in Aid No. 63609005f or Scientific Research on Priority Area of the Ministry of Education of Japan. The authors appreciate the financial supports by Yamada Science Foundation, Murata Science Foundation and CASIO Science Promotion Fund. Copyright: Copyright 2014 Elsevier B.V., All rights reserved.

PY - 1990/5/3

Y1 - 1990/5/3

N2 - A nitrogen overlayer (N(a)) was synthesized on Pd(100) by catalytic reduction of NO by CO or H2 in the total pressure range of 10-7-101 Torr at crystal temperatures higher than 500 K. The process of the formation of N(a) was monitored by AES, LEED, HREELS and TDS. N(a) formed a c(2 × 2) superlattice, and desorbed at 600-700 K. N(a) was hydrogenated by gas-phase H2. HREELS revealed the reversible formation of NHx(a) species on the surface.

AB - A nitrogen overlayer (N(a)) was synthesized on Pd(100) by catalytic reduction of NO by CO or H2 in the total pressure range of 10-7-101 Torr at crystal temperatures higher than 500 K. The process of the formation of N(a) was monitored by AES, LEED, HREELS and TDS. N(a) formed a c(2 × 2) superlattice, and desorbed at 600-700 K. N(a) was hydrogenated by gas-phase H2. HREELS revealed the reversible formation of NHx(a) species on the surface.

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DO - 10.1016/0039-6028(90)90199-I

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VL - 231

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EP - 314

JO - Surface Science

JF - Surface Science

SN - 0039-6028

IS - 3

ER -

Formation of a c(2 × 2) overlayer of nitrogen on Pd(100) by NO + CO reaction or NO + H₂ reaction

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ASJC Scopus subject areas

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