TY - JOUR
T1 - Formation and decay of core-orbital vacancies in the water molecule
AU - Mucke, M.
AU - Eland, J. H.D.
AU - Takahashi, O.
AU - Linusson, P.
AU - Lebrun, D.
AU - Ueda, K.
AU - Feifel, R.
N1 - Funding Information:
This work has been financially supported by the Swedish Research Council (VR), the Göran Gustafsson Foundation (UU/KTH), and the Knut and Alice Wallenberg Foundation , Sweden. We would like to warmly acknowledge the support by the staff and colleagues at BESSY-II, Berlin. This work was also supported by the European Community – Research Infrastructure Action under the FP6 ”Structuring the European Research Area” Programme (through the Integrated Infrastructure Initiative ”Integrating Activity on Synchroton and Free Electron Laser Science” – Contract R II 3-CT-2004–506008).
PY - 2013/2/12
Y1 - 2013/2/12
N2 - Primary steps in the interaction of high energy photons with water creating multiply ionised products are examined experimentally and theoretically. Double Auger decay from a 1s-hole state populates triply ionised states between 80 and 140 eV binding energy. Ejection of one 1s electron and one valence electron gives states around 570 eV which decay to triply ionised states between 75 and 110 eV. Nuclear motion in these states competes with Auger decay and substantially modifies the final state spectra. The double core-hole state from ionisation of both 1s electrons is found at 1171 ± 1 eV and calculated at 1170.85 eV.
AB - Primary steps in the interaction of high energy photons with water creating multiply ionised products are examined experimentally and theoretically. Double Auger decay from a 1s-hole state populates triply ionised states between 80 and 140 eV binding energy. Ejection of one 1s electron and one valence electron gives states around 570 eV which decay to triply ionised states between 75 and 110 eV. Nuclear motion in these states competes with Auger decay and substantially modifies the final state spectra. The double core-hole state from ionisation of both 1s electrons is found at 1171 ± 1 eV and calculated at 1170.85 eV.
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U2 - 10.1016/j.cplett.2012.11.094
DO - 10.1016/j.cplett.2012.11.094
M3 - Article
AN - SCOPUS:84873183578
VL - 558
SP - 82
EP - 87
JO - Chemical Physics Letters
JF - Chemical Physics Letters
SN - 0009-2614
ER -