Formation and bioactivation of Zr-Al-Co bulk metallic glasses

Takeshi Wada, Fengxiang Qin, Xinmin Wang, Masahiro Yoshimura, Akihisa Inoue, Naota Sugiyama, Rieko Ito, Nobuhiro Matsushita

Research output: Contribution to journalArticlepeer-review

100 Citations (Scopus)


A Cu- and Ni-free Zr-based metallic glass with high glass-forming ability was found in the Zr-Al-Co ternary system. The eutectic Zr56Al 16Co28 alloy could be cast into glassy cylindrical rods with diameters up to 18 mm. The glassy alloy exhibited high tensile fracture strength of 1830 MPa and low Young's modulus of 83 GPa in conjunction with better corrosion resistance compared with the glassy Zr57Nb 5Al10Ni12.6Cu15.4 in a simulated body fluid. Hydrothermal-electrochemical treatment in the aqueous 5M-NaOH solution resulted in the formation of amorphous sodium cobaltate layer on the surface of glassy Zr56Al16Co28 alloy. Hydroxyapatite was spontaneously formed on the surface of the alloy, indicating bioactivity after surface modification. The discovery of a Cu- and Ni-free Zr-based metallic glass with a critical diameter larger than 1 cm in conjunction with excellent mechanical properties, superior corrosion resistance, and good bioactivity may open up the application field as biomaterials.

Original languageEnglish
Pages (from-to)2941-2948
Number of pages8
JournalJournal of Materials Research
Issue number9
Publication statusPublished - 2009 Sep

ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering


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