Fluorine K-shell photoelectron angular distribution from CF4 molecules in the molecular frame

H. Fukuzawa, X. J. Liu, T. Teranishi, K. Sakai, G. Prümper, K. Ueda, Y. Morishita, N. Saito, M. Stener, P. Decleva

Research output: Contribution to journalArticlepeer-review

7 Citations (Scopus)

Abstract

Molecular-frame photoelectron angular distributions (MFPADs) for CF4 in the fluorine K-shell ionization region have been measured at three photon energies 705, 725 and 775 eV. The molecular axis was defined by the momenta of the F+ s(-) CF3+ ions detected in coincidence. The MFPADs were compared with ab initio calculations using the time dependent density functional theory. The results of a calculation assuming a localized F 1s core-hole agree better with the observed MFPADs than the results of a calculation using a delocalized core-hole, especially for 775 eV.

Original languageEnglish
Pages (from-to)182-185
Number of pages4
JournalChemical Physics Letters
Volume451
Issue number4-6
DOIs
Publication statusPublished - 2008 Jan 21

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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