Fluorine K-shell photoelectron angular distribution from CF4 molecules in the molecular frame

H. Fukuzawa; X. J. Liu; T. Teranishi; K. Sakai; G. Prümper; K. Ueda; Y. Morishita; N. Saito; M. Stener; P. Decleva

doi:10.1016/j.cplett.2007.11.085

Fluorine K-shell photoelectron angular distribution from CF₄ molecules in the molecular frame

H. Fukuzawa, X. J. Liu, T. Teranishi, K. Sakai, G. Prümper, K. Ueda, Y. Morishita, N. Saito, M. Stener, P. Decleva

Division of Measurements

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

Molecular-frame photoelectron angular distributions (MFPADs) for CF₄ in the fluorine K-shell ionization region have been measured at three photon energies 705, 725 and 775 eV. The molecular axis was defined by the momenta of the F⁺ s(-) CF₃⁺ ions detected in coincidence. The MFPADs were compared with ab initio calculations using the time dependent density functional theory. The results of a calculation assuming a localized F 1s core-hole agree better with the observed MFPADs than the results of a calculation using a delocalized core-hole, especially for 775 eV.

Original language	English
Pages (from-to)	182-185
Number of pages	4
Journal	Chemical Physics Letters
Volume	451
Issue number	4-6
DOIs	https://doi.org/10.1016/j.cplett.2007.11.085
Publication status	Published - 2008 Jan 21

ASJC Scopus subject areas

Physics and Astronomy(all)
Physical and Theoretical Chemistry

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@article{2203918118474ce08a2a6e9c22529e5b,

title = "Fluorine K-shell photoelectron angular distribution from CF4 molecules in the molecular frame",

abstract = "Molecular-frame photoelectron angular distributions (MFPADs) for CF4 in the fluorine K-shell ionization region have been measured at three photon energies 705, 725 and 775 eV. The molecular axis was defined by the momenta of the F+ s(-) CF3+ ions detected in coincidence. The MFPADs were compared with ab initio calculations using the time dependent density functional theory. The results of a calculation assuming a localized F 1s core-hole agree better with the observed MFPADs than the results of a calculation using a delocalized core-hole, especially for 775 eV.",

author = "H. Fukuzawa and Liu, {X. J.} and T. Teranishi and K. Sakai and G. Pr{\"u}mper and K. Ueda and Y. Morishita and N. Saito and M. Stener and P. Decleva",

year = "2008",

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language = "English",

volume = "451",

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T1 - Fluorine K-shell photoelectron angular distribution from CF4 molecules in the molecular frame

AU - Fukuzawa, H.

AU - Liu, X. J.

AU - Teranishi, T.

AU - Sakai, K.

AU - Prümper, G.

AU - Ueda, K.

AU - Morishita, Y.

AU - Saito, N.

AU - Stener, M.

AU - Decleva, P.

PY - 2008/1/21

Y1 - 2008/1/21

N2 - Molecular-frame photoelectron angular distributions (MFPADs) for CF4 in the fluorine K-shell ionization region have been measured at three photon energies 705, 725 and 775 eV. The molecular axis was defined by the momenta of the F+ s(-) CF3+ ions detected in coincidence. The MFPADs were compared with ab initio calculations using the time dependent density functional theory. The results of a calculation assuming a localized F 1s core-hole agree better with the observed MFPADs than the results of a calculation using a delocalized core-hole, especially for 775 eV.

AB - Molecular-frame photoelectron angular distributions (MFPADs) for CF4 in the fluorine K-shell ionization region have been measured at three photon energies 705, 725 and 775 eV. The molecular axis was defined by the momenta of the F+ s(-) CF3+ ions detected in coincidence. The MFPADs were compared with ab initio calculations using the time dependent density functional theory. The results of a calculation assuming a localized F 1s core-hole agree better with the observed MFPADs than the results of a calculation using a delocalized core-hole, especially for 775 eV.

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