First single crystal growth of the transuranium filled-skutterudite compound NpFe4P12 and its magnetic and electrical properties

Dai Aoki, Yoshinori Haga, Yoshiya Homma, Hironori Sakai, Shugo Ikeda, Yoshinobu Shiokawa, Etsuji Yamamoto, Akio Nakamura, Yoshichika Onuki

Research output: Contribution to journalArticlepeer-review

10 Citations (Scopus)

Abstract

We succeeded in growing single crystals of NpFe4P12 using the Sn-flux method and measured the electrical resistivity, magnetic susceptibility, magnetization, and specific heat. This is the first single crystal growth of transuranium filled-skutterudite compounds. NpFe 4P12 is found to order ferromagnetically below T C = 23 K. The magnetic moment is directed along the (100) direction with the saturated moment of 1.35 μB/Np. The large resistivity value indicates that NpFe4P12 might be a semimetal, where the 5f electrons are localized with a 5f3 configuration, indicating Np4+. The electronic specific heat coefficient γ is found to be small, γ ≃ 10 mJ/(K2·mol), which is consistent with the low carrier system.

Original languageEnglish
Article number073703
Journaljournal of the physical society of japan
Volume75
Issue number7
DOIs
Publication statusPublished - 2006 Jul

Keywords

  • Filled-skutterudite compound
  • Magnetization
  • NpFeP
  • Resistivity
  • Specific heat
  • Transuranium compound

ASJC Scopus subject areas

  • Physics and Astronomy(all)

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