First acid dissociation at an aqueous H2SO4 interface with sum frequency generation spectroscopy

Takayuki Miyamae; Akihiro Morita; Yukio Ouchi

doi:10.1039/b719496j

First acid dissociation at an aqueous H₂SO₄ interface with sum frequency generation spectroscopy

Takayuki Miyamae, Akihiro Morita, Yukio Ouchi

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

The vibrational sum frequency generation (SFG) spectra of the air-liquid interface of H₂SO₄-H₂O solutions over a wide range of concentrations are measured in the SO stretching region (1000-1300 cm^-1). The analogy of the concentration dependence of Raman and SFG is indicative of a nearly identical behavior of the first acid dissociation at the air-liquid interface as in the bulk.

Original language	English
Pages (from-to)	2010-2013
Number of pages	4
Journal	Physical Chemistry Chemical Physics
Volume	10
Issue number	15
DOIs	https://doi.org/10.1039/b719496j
Publication status	Published - 2008 Apr 9
Externally published	Yes

ASJC Scopus subject areas

Physics and Astronomy(all)
Physical and Theoretical Chemistry

Access to Document

10.1039/b719496j

Cite this

@article{fff725ab75a8451e8c43f2825d96e46d,

title = "First acid dissociation at an aqueous H2SO4 interface with sum frequency generation spectroscopy",

abstract = "The vibrational sum frequency generation (SFG) spectra of the air-liquid interface of H2SO4-H2O solutions over a wide range of concentrations are measured in the SO stretching region (1000-1300 cm-1). The analogy of the concentration dependence of Raman and SFG is indicative of a nearly identical behavior of the first acid dissociation at the air-liquid interface as in the bulk.",

author = "Takayuki Miyamae and Akihiro Morita and Yukio Ouchi",

year = "2008",

month = apr,

day = "9",

doi = "10.1039/b719496j",

language = "English",

volume = "10",

pages = "2010--2013",

journal = "Physical Chemistry Chemical Physics",

issn = "1463-9076",

publisher = "Royal Society of Chemistry",

number = "15",

}

TY - JOUR

T1 - First acid dissociation at an aqueous H2SO4 interface with sum frequency generation spectroscopy

AU - Miyamae, Takayuki

AU - Morita, Akihiro

AU - Ouchi, Yukio

PY - 2008/4/9

Y1 - 2008/4/9

N2 - The vibrational sum frequency generation (SFG) spectra of the air-liquid interface of H2SO4-H2O solutions over a wide range of concentrations are measured in the SO stretching region (1000-1300 cm-1). The analogy of the concentration dependence of Raman and SFG is indicative of a nearly identical behavior of the first acid dissociation at the air-liquid interface as in the bulk.

AB - The vibrational sum frequency generation (SFG) spectra of the air-liquid interface of H2SO4-H2O solutions over a wide range of concentrations are measured in the SO stretching region (1000-1300 cm-1). The analogy of the concentration dependence of Raman and SFG is indicative of a nearly identical behavior of the first acid dissociation at the air-liquid interface as in the bulk.

UR - http://www.scopus.com/inward/record.url?scp=41549093685&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=41549093685&partnerID=8YFLogxK

U2 - 10.1039/b719496j

DO - 10.1039/b719496j

M3 - Article

C2 - 18688352

AN - SCOPUS:41549093685

VL - 10

SP - 2010

EP - 2013

JO - Physical Chemistry Chemical Physics

JF - Physical Chemistry Chemical Physics

SN - 1463-9076

IS - 15

ER -

First acid dissociation at an aqueous H₂SO₄ interface with sum frequency generation spectroscopy

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this