Abstract
The vibrational sum frequency generation (SFG) spectra of the air-liquid interface of H2SO4-H2O solutions over a wide range of concentrations are measured in the SO stretching region (1000-1300 cm-1). The analogy of the concentration dependence of Raman and SFG is indicative of a nearly identical behavior of the first acid dissociation at the air-liquid interface as in the bulk.
| Original language | English |
|---|---|
| Pages (from-to) | 2010-2013 |
| Number of pages | 4 |
| Journal | Physical Chemistry Chemical Physics |
| Volume | 10 |
| Issue number | 15 |
| DOIs | |
| Publication status | Published - 2008 Apr 9 |
ASJC Scopus subject areas
- Physics and Astronomy(all)
- Physical and Theoretical Chemistry
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Miyamae, T., Morita, A., & Ouchi, Y. (2008). First acid dissociation at an aqueous H2SO4 interface with sum frequency generation spectroscopy. Physical Chemistry Chemical Physics, 10(15), 2010-2013. https://doi.org/10.1039/b719496j