Fine tuning of intra-lattice electron transfers through site doping in tetraoxolene-bridged iron honeycomb layers

Yoshihiro Sekine, Jian Chen, Naoki Eguchi, Hitoshi Miyasaka

Research output: Contribution to journalArticlepeer-review

1 Citation (Scopus)

Abstract

The precise control of intra-lattice multiple electron transfers was demonstrated in the solvated and desolvated species of the tetraoxolene-bridged Fe honeycomb layer system, (NPr4)2[Fe2(Cl2An)3]·(solv) (Cl2Ann−= 2,5-dichloro-3,6-dihydroxy-1,4-benzoquinonate; NPr4+= tetrapropylammonium cation), by the site-doping of the Cl2Ann−bridging unit using X2Ann−units with X = Br or F.

Original languageEnglish
Pages (from-to)10867-10870
Number of pages4
JournalChemical Communications
Volume56
Issue number74
DOIs
Publication statusPublished - 2020 Sep 21

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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