Fine tuning of intra-lattice electron transfers through site doping in tetraoxolene-bridged iron honeycomb layers

Yoshihiro Sekine; Jian Chen; Naoki Eguchi; Hitoshi Miyasaka

doi:10.1039/d0cc03808c

Fine tuning of intra-lattice electron transfers through site doping in tetraoxolene-bridged iron honeycomb layers

Yoshihiro Sekine, Jian Chen, Naoki Eguchi, Hitoshi Miyasaka

Materials Development Division

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

The precise control of intra-lattice multiple electron transfers was demonstrated in the solvated and desolvated species of the tetraoxolene-bridged Fe honeycomb layer system, (NPr₄)₂[Fe₂(Cl₂An)₃]·(solv) (Cl₂Anⁿ⁻= 2,5-dichloro-3,6-dihydroxy-1,4-benzoquinonate; NPr₄⁺= tetrapropylammonium cation), by the site-doping of the Cl₂Anⁿ⁻bridging unit using X₂Anⁿ⁻units with X = Br or F.

Original language	English
Pages (from-to)	10867-10870
Number of pages	4
Journal	Chemical Communications
Volume	56
Issue number	74
DOIs	https://doi.org/10.1039/d0cc03808c
Publication status	Published - 2020 Sep 21

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "Fine tuning of intra-lattice electron transfers through site doping in tetraoxolene-bridged iron honeycomb layers",

abstract = "The precise control of intra-lattice multiple electron transfers was demonstrated in the solvated and desolvated species of the tetraoxolene-bridged Fe honeycomb layer system, (NPr4)2[Fe2(Cl2An)3]·(solv) (Cl2Ann−= 2,5-dichloro-3,6-dihydroxy-1,4-benzoquinonate; NPr4+= tetrapropylammonium cation), by the site-doping of the Cl2Ann−bridging unit using X2Ann−units with X = Br or F.",

author = "Yoshihiro Sekine and Jian Chen and Naoki Eguchi and Hitoshi Miyasaka",

year = "2020",

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doi = "10.1039/d0cc03808c",

language = "English",

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journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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T1 - Fine tuning of intra-lattice electron transfers through site doping in tetraoxolene-bridged iron honeycomb layers

AU - Sekine, Yoshihiro

AU - Chen, Jian

AU - Eguchi, Naoki

AU - Miyasaka, Hitoshi

PY - 2020/9/21

Y1 - 2020/9/21

N2 - The precise control of intra-lattice multiple electron transfers was demonstrated in the solvated and desolvated species of the tetraoxolene-bridged Fe honeycomb layer system, (NPr4)2[Fe2(Cl2An)3]·(solv) (Cl2Ann−= 2,5-dichloro-3,6-dihydroxy-1,4-benzoquinonate; NPr4+= tetrapropylammonium cation), by the site-doping of the Cl2Ann−bridging unit using X2Ann−units with X = Br or F.

AB - The precise control of intra-lattice multiple electron transfers was demonstrated in the solvated and desolvated species of the tetraoxolene-bridged Fe honeycomb layer system, (NPr4)2[Fe2(Cl2An)3]·(solv) (Cl2Ann−= 2,5-dichloro-3,6-dihydroxy-1,4-benzoquinonate; NPr4+= tetrapropylammonium cation), by the site-doping of the Cl2Ann−bridging unit using X2Ann−units with X = Br or F.

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JO - Chemical Communications

JF - Chemical Communications

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