Film preparation of siloxane-based polymer containing anthracene group

Ali Demirci; Jun Matsui; Masaya Mitsuishi; Akira Watanabe; Tokuji Miyashita

doi:10.1080/15421406.2013.805066

Film preparation of siloxane-based polymer containing anthracene group

Ali Demirci, Jun Matsui, Masaya Mitsuishi, Akira Watanabe, Tokuji Miyashita

Polymer Hybrid Materials Research Center

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

Siloxane-based polymer was synthesized through hydrosilylation of the 1,3,5,7-tetramethylcyclotetrasiloxane (TMCS) and 1,3-divinyltetramethylsiloxane (DTMS). Controlling the hydrosilylation reaction by varying the feeding ratio with the total monomer concentration, chemically-soluble siloxane-based polymer was obtained, which allowed film preparation as well as further incorporation of functional groups through the hydrosilylation reaction. The incorporation of 9-vinylanthracene was succesfully carried out by reacting Si-H groups of the TMCS-DTMS polymer with the vinyl-terminated anthracene derivative. Structural and thermal properties of the polymer were evaluated using NMR, GPC, FT-IR and flourecence spectroscopy.

Original language	English
Pages (from-to)	34-38
Number of pages	5
Journal	Molecular crystals and liquid crystals
Volume	579
Issue number	1
DOIs	https://doi.org/10.1080/15421406.2013.805066
Publication status	Published - 2013 Sep 1

Keywords

Anthracene
hybrid polymer
hydrosilylation
siloxane

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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title = "Film preparation of siloxane-based polymer containing anthracene group",

abstract = "Siloxane-based polymer was synthesized through hydrosilylation of the 1,3,5,7-tetramethylcyclotetrasiloxane (TMCS) and 1,3-divinyltetramethylsiloxane (DTMS). Controlling the hydrosilylation reaction by varying the feeding ratio with the total monomer concentration, chemically-soluble siloxane-based polymer was obtained, which allowed film preparation as well as further incorporation of functional groups through the hydrosilylation reaction. The incorporation of 9-vinylanthracene was succesfully carried out by reacting Si-H groups of the TMCS-DTMS polymer with the vinyl-terminated anthracene derivative. Structural and thermal properties of the polymer were evaluated using NMR, GPC, FT-IR and flourecence spectroscopy.",

keywords = "Anthracene, hybrid polymer, hydrosilylation, siloxane",

author = "Ali Demirci and Jun Matsui and Masaya Mitsuishi and Akira Watanabe and Tokuji Miyashita",

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T1 - Film preparation of siloxane-based polymer containing anthracene group

AU - Demirci, Ali

AU - Matsui, Jun

AU - Mitsuishi, Masaya

AU - Watanabe, Akira

AU - Miyashita, Tokuji

PY - 2013/9/1

Y1 - 2013/9/1

N2 - Siloxane-based polymer was synthesized through hydrosilylation of the 1,3,5,7-tetramethylcyclotetrasiloxane (TMCS) and 1,3-divinyltetramethylsiloxane (DTMS). Controlling the hydrosilylation reaction by varying the feeding ratio with the total monomer concentration, chemically-soluble siloxane-based polymer was obtained, which allowed film preparation as well as further incorporation of functional groups through the hydrosilylation reaction. The incorporation of 9-vinylanthracene was succesfully carried out by reacting Si-H groups of the TMCS-DTMS polymer with the vinyl-terminated anthracene derivative. Structural and thermal properties of the polymer were evaluated using NMR, GPC, FT-IR and flourecence spectroscopy.

AB - Siloxane-based polymer was synthesized through hydrosilylation of the 1,3,5,7-tetramethylcyclotetrasiloxane (TMCS) and 1,3-divinyltetramethylsiloxane (DTMS). Controlling the hydrosilylation reaction by varying the feeding ratio with the total monomer concentration, chemically-soluble siloxane-based polymer was obtained, which allowed film preparation as well as further incorporation of functional groups through the hydrosilylation reaction. The incorporation of 9-vinylanthracene was succesfully carried out by reacting Si-H groups of the TMCS-DTMS polymer with the vinyl-terminated anthracene derivative. Structural and thermal properties of the polymer were evaluated using NMR, GPC, FT-IR and flourecence spectroscopy.

KW - Anthracene

KW - hybrid polymer

KW - hydrosilylation

KW - siloxane

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