TY - JOUR
T1 - Film preparation of siloxane-based polymer containing anthracene group
AU - Demirci, Ali
AU - Matsui, Jun
AU - Mitsuishi, Masaya
AU - Watanabe, Akira
AU - Miyashita, Tokuji
N1 - Copyright:
Copyright 2013 Elsevier B.V., All rights reserved.
PY - 2013/9/1
Y1 - 2013/9/1
N2 - Siloxane-based polymer was synthesized through hydrosilylation of the 1,3,5,7-tetramethylcyclotetrasiloxane (TMCS) and 1,3-divinyltetramethylsiloxane (DTMS). Controlling the hydrosilylation reaction by varying the feeding ratio with the total monomer concentration, chemically-soluble siloxane-based polymer was obtained, which allowed film preparation as well as further incorporation of functional groups through the hydrosilylation reaction. The incorporation of 9-vinylanthracene was succesfully carried out by reacting Si-H groups of the TMCS-DTMS polymer with the vinyl-terminated anthracene derivative. Structural and thermal properties of the polymer were evaluated using NMR, GPC, FT-IR and flourecence spectroscopy.
AB - Siloxane-based polymer was synthesized through hydrosilylation of the 1,3,5,7-tetramethylcyclotetrasiloxane (TMCS) and 1,3-divinyltetramethylsiloxane (DTMS). Controlling the hydrosilylation reaction by varying the feeding ratio with the total monomer concentration, chemically-soluble siloxane-based polymer was obtained, which allowed film preparation as well as further incorporation of functional groups through the hydrosilylation reaction. The incorporation of 9-vinylanthracene was succesfully carried out by reacting Si-H groups of the TMCS-DTMS polymer with the vinyl-terminated anthracene derivative. Structural and thermal properties of the polymer were evaluated using NMR, GPC, FT-IR and flourecence spectroscopy.
KW - Anthracene
KW - hybrid polymer
KW - hydrosilylation
KW - siloxane
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U2 - 10.1080/15421406.2013.805066
DO - 10.1080/15421406.2013.805066
M3 - Article
AN - SCOPUS:84884569131
VL - 579
SP - 34
EP - 38
JO - Molecular Crystals and Liquid Crystals
JF - Molecular Crystals and Liquid Crystals
SN - 1542-1406
IS - 1
ER -