Film preparation of siloxane-based polymer containing anthracene group

Ali Demirci, Jun Matsui, Masaya Mitsuishi, Akira Watanabe, Tokuji Miyashita

    Research output: Contribution to journalArticlepeer-review

    2 Citations (Scopus)

    Abstract

    Siloxane-based polymer was synthesized through hydrosilylation of the 1,3,5,7-tetramethylcyclotetrasiloxane (TMCS) and 1,3-divinyltetramethylsiloxane (DTMS). Controlling the hydrosilylation reaction by varying the feeding ratio with the total monomer concentration, chemically-soluble siloxane-based polymer was obtained, which allowed film preparation as well as further incorporation of functional groups through the hydrosilylation reaction. The incorporation of 9-vinylanthracene was succesfully carried out by reacting Si-H groups of the TMCS-DTMS polymer with the vinyl-terminated anthracene derivative. Structural and thermal properties of the polymer were evaluated using NMR, GPC, FT-IR and flourecence spectroscopy.

    Original languageEnglish
    Pages (from-to)34-38
    Number of pages5
    JournalMolecular crystals and liquid crystals
    Volume579
    Issue number1
    DOIs
    Publication statusPublished - 2013 Sep 1

    Keywords

    • Anthracene
    • hybrid polymer
    • hydrosilylation
    • siloxane

    ASJC Scopus subject areas

    • Chemistry(all)
    • Materials Science(all)
    • Condensed Matter Physics

    Fingerprint

    Dive into the research topics of 'Film preparation of siloxane-based polymer containing anthracene group'. Together they form a unique fingerprint.

    Cite this