Abstract
Siloxane-based polymer was synthesized through hydrosilylation of the 1,3,5,7-tetramethylcyclotetrasiloxane (TMCS) and 1,3-divinyltetramethylsiloxane (DTMS). Controlling the hydrosilylation reaction by varying the feeding ratio with the total monomer concentration, chemically-soluble siloxane-based polymer was obtained, which allowed film preparation as well as further incorporation of functional groups through the hydrosilylation reaction. The incorporation of 9-vinylanthracene was succesfully carried out by reacting Si-H groups of the TMCS-DTMS polymer with the vinyl-terminated anthracene derivative. Structural and thermal properties of the polymer were evaluated using NMR, GPC, FT-IR and flourecence spectroscopy.
| Original language | English |
|---|---|
| Pages (from-to) | 34-38 |
| Number of pages | 5 |
| Journal | Molecular crystals and liquid crystals |
| Volume | 579 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - 2013 Sep 1 |
Keywords
- Anthracene
- hybrid polymer
- hydrosilylation
- siloxane
ASJC Scopus subject areas
- Chemistry(all)
- Materials Science(all)
- Condensed Matter Physics
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Cite this
Demirci, A., Matsui, J., Mitsuishi, M., Watanabe, A., & Miyashita, T. (2013). Film preparation of siloxane-based polymer containing anthracene group. Molecular crystals and liquid crystals, 579(1), 34-38. https://doi.org/10.1080/15421406.2013.805066