Film preparation of siloxane-based polymer containing anthracene group

Ali Demirci, Jun Matsui, Masaya Mitsuishi, Akira Watanabe, Tokuji Miyashita

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

Siloxane-based polymer was synthesized through hydrosilylation of the 1,3,5,7-tetramethylcyclotetrasiloxane (TMCS) and 1,3-divinyltetramethylsiloxane (DTMS). Controlling the hydrosilylation reaction by varying the feeding ratio with the total monomer concentration, chemically-soluble siloxane-based polymer was obtained, which allowed film preparation as well as further incorporation of functional groups through the hydrosilylation reaction. The incorporation of 9-vinylanthracene was succesfully carried out by reacting Si-H groups of the TMCS-DTMS polymer with the vinyl-terminated anthracene derivative. Structural and thermal properties of the polymer were evaluated using NMR, GPC, FT-IR and flourecence spectroscopy.

Original languageEnglish
Pages (from-to)34-38
Number of pages5
JournalMolecular crystals and liquid crystals
Volume579
Issue number1
DOIs
Publication statusPublished - 2013 Sep 1

Keywords

  • Anthracene
  • hybrid polymer
  • hydrosilylation
  • siloxane

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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