Filled skutterudite structure of europium ruthenium polyphosphide, EuRu4P12

Isao Kagomiya, Shiro Funahashi, Terutoshi Sakakura, Takashi Komori, Kiyoaki Tanaka

Research output: Contribution to journalArticlepeer-review

1 Citation (Scopus)

Abstract

The crystal structure of EuRu4P12 is isotypic with filled skutterudite structures of rare earth transition metal poly-phosphides: RFe4P12 (R = Ce, Pr, Nd, Sm and Eu), RRu4P 12 (R = La, Ce, Pr and Nd) and ROs4P12 (R = La, Ce, Pr and Nd). The Ru cation is coordinated by six P anions in a distorted octa-hedral manner. The partially occupied Eu position (site occupancy 0.97) is enclosed by a cage formed by the corner-shared framework of the eight RuP 6 octa-hedra.

Original languageEnglish
Pages (from-to)i6
JournalActa Crystallographica Section E: Structure Reports Online
Volume66
Issue number2
DOIs
Publication statusPublished - 2010

Keywords

  • Data-to-parameter ratio = 43.5
  • Disorder in main residue
  • Mean σ(Ru-P) = 0.0003Å
  • R factor = 0.020
  • Single-crystal X-ray study
  • T = 100 K
  • WR factor = 0.024

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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