FIB-SEM and TEMT observation of highly elastic rubbery material with nanomatrix structure

Seiichi Kawahara, Yoshimasa Yamamoto, Shuji Fujii, Yoshinobu Isono, Ken Ichi Niihara, Hiroshi Jinnai, Hideo Nishioka, Akio Takaoka

Research output: Contribution to journalArticle

30 Citations (Scopus)

Abstract

A relationship between viscoelastic properties and morphology of the nanomatrix-structured material, in comparison with that of the island-matrix structured material, in which the nanomatrix structure and island-matrix structure were formed by graft-polymerization of styrene onto natural rubber latex, was investigated. Three-dimensional observation of the nanomatrix structure was carried out with a field emission scanning electron microscopy equipped with focused ion beam (FIB-SEM) and transmission electron microscope (TEM) and transmission electron microtomography (TEMT). It was observed when nanomatrix structure was formed in natural rubber, the value of plateau modulus of rubber significantly increased in comparison to that of natural rubber. Meanwhile, the plateau modulus increased slightly when the island-matrix structure was formed in natural rubber. Nanomatrix structures was proven to be a suitable structure to improve the viscoelastic property of rubbery material.

Original languageEnglish
Pages (from-to)4510-4513
Number of pages4
JournalMacromolecules
Volume41
Issue number12
DOIs
Publication statusPublished - 2008 Jun 24
Externally publishedYes

ASJC Scopus subject areas

  • Organic Chemistry
  • Polymers and Plastics
  • Inorganic Chemistry
  • Materials Chemistry

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  • Cite this

    Kawahara, S., Yamamoto, Y., Fujii, S., Isono, Y., Niihara, K. I., Jinnai, H., Nishioka, H., & Takaoka, A. (2008). FIB-SEM and TEMT observation of highly elastic rubbery material with nanomatrix structure. Macromolecules, 41(12), 4510-4513. https://doi.org/10.1021/ma7028538