FeSiBP bulk metallic glasses with high magnetization and excellent magnetic softness

Akihiro Makino, Takeshi Kubota, Chuntao Chang, Masahiro Makabe, Akihisa Inoue

Research output: Contribution to journalArticlepeer-review

90 Citations (Scopus)

Abstract

Fe-based amorphous alloy ribbons are one of the major soft magnetic materials, because of their superior magnetic properties such as the relatively high saturation magnetization (Js) of 1.5-1.6 T and good magnetic softness. However, the preparation of the ordinary amorphous magnetic alloys requires cooling rates higher than 104 K/s due to the low glass-forming ability (GFA) and thus restricts the material outer shape. Recently, Fe-metalloid-based bulk metallic glasses (BMGs) containing glass-forming elements such as Al, Ga, Nb, Mo, Y and so forth have been developed. These alloys have high GFA, leading to the formation of BMG rod with diameters of mm-order. However, the glass-forming metal elements in BMGs result in a remarkable decrease in magnetization. Basically, Js depends on Fe content; hence, high Js requires high Fe content in the Fe-based amorphous alloys or BMGs. On the other hand, high GFA requires a large amount of glass-forming elements in the alloys, which results in lower Fe content. Therefore, in substances, the coexistence of high Js and high GFA is difficult. Since this matter should be immensely important from academia to industry in the material field, a great deal of effort has been devoted; however, it has remained unsolved for many years. In this paper, we present a novel Fe-rich FeSiBP BMG with high Js of 1.51 T comparable to the ordinary Fe-Si-B amorphous alloy now in practical use as well as with high GFA leading to a rod-shaped specimen of 2.5 mm in diameter, obtained by Cu-mold casting in air.

Original languageEnglish
Pages (from-to)2499-2503
Number of pages5
JournalJournal of Magnetism and Magnetic Materials
Volume320
Issue number20
DOIs
Publication statusPublished - 2008 Oct 1

Keywords

  • Amorphous-forming ability
  • High saturation magnetization
  • Iron-based glassy alloy
  • Magnetic softness

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics

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