Ferromagnetic assemblies composed of Mn III salen-type complexes and a tripodal Fe III complex with an imidazolate bridge

Ryuta Ishikawa, Hitoshi Miyasaka, Masahiro Yamashita

Research output: Contribution to journalArticle

Abstract

The use of a low-spin Fe III complex bearing three imidazolate groups in a reaction with Mn III salen-type complexes provided two different imidazolate-bridged Mn IIIFe III assemblies, a dinuclear complex and a onedimensional chain, dependent on the salen ligand and counter ion used. Both compounds exhibit a ferromagnetic exchange between Mn III and Fe III centers via the imidazolate linkage.

Original languageEnglish
Pages (from-to)816-818
Number of pages3
JournalBulletin of the Chemical Society of Japan
Volume82
Issue number7
DOIs
Publication statusPublished - 2009 Aug 4

ASJC Scopus subject areas

  • Chemistry(all)

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