Ferromagnetic assemblies composed of Mn III salen-type complexes and a tripodal Fe III complex with an imidazolate bridge

Ryuta Ishikawa; Hitoshi Miyasaka; Masahiro Yamashita

doi:10.1246/bcsj.82.816

Ferromagnetic assemblies composed of Mn _III salen-type complexes and a tripodal Fe _III complex with an imidazolate bridge

Ryuta Ishikawa, Hitoshi Miyasaka, Masahiro Yamashita

Research output: Contribution to journal › Article › peer-review

Abstract

The use of a low-spin Fe _III complex bearing three imidazolate groups in a reaction with Mn _III salen-type complexes provided two different imidazolate-bridged Mn _IIIFe _III assemblies, a dinuclear complex and a onedimensional chain, dependent on the salen ligand and counter ion used. Both compounds exhibit a ferromagnetic exchange between Mn _III and Fe _III centers via the imidazolate linkage.

Original language	English
Pages (from-to)	816-818
Number of pages	3
Journal	Bulletin of the Chemical Society of Japan
Volume	82
Issue number	7
DOIs	https://doi.org/10.1246/bcsj.82.816
Publication status	Published - 2009 Aug 4

ASJC Scopus subject areas

Chemistry(all)

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abstract = "The use of a low-spin Fe III complex bearing three imidazolate groups in a reaction with Mn III salen-type complexes provided two different imidazolate-bridged Mn IIIFe III assemblies, a dinuclear complex and a onedimensional chain, dependent on the salen ligand and counter ion used. Both compounds exhibit a ferromagnetic exchange between Mn III and Fe III centers via the imidazolate linkage.",

author = "Ryuta Ishikawa and Hitoshi Miyasaka and Masahiro Yamashita",

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AU - Ishikawa, Ryuta

AU - Miyasaka, Hitoshi

AU - Yamashita, Masahiro

PY - 2009/8/4

Y1 - 2009/8/4

N2 - The use of a low-spin Fe III complex bearing three imidazolate groups in a reaction with Mn III salen-type complexes provided two different imidazolate-bridged Mn IIIFe III assemblies, a dinuclear complex and a onedimensional chain, dependent on the salen ligand and counter ion used. Both compounds exhibit a ferromagnetic exchange between Mn III and Fe III centers via the imidazolate linkage.

AB - The use of a low-spin Fe III complex bearing three imidazolate groups in a reaction with Mn III salen-type complexes provided two different imidazolate-bridged Mn IIIFe III assemblies, a dinuclear complex and a onedimensional chain, dependent on the salen ligand and counter ion used. Both compounds exhibit a ferromagnetic exchange between Mn III and Fe III centers via the imidazolate linkage.

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Ferromagnetic assemblies composed of Mn _III salen-type complexes and a tripodal Fe _III complex with an imidazolate bridge

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