Ferrocenyl-substituted bicyclo[1.1.1]pentasilanes: Evaluation of significant interactions between ferrocenyl units and rigid silicon cages

Yusuke Kishimoto; Shintaro Ishida; Takeaki Iwamoto

doi:10.1246/cl.151089

Ferrocenyl-substituted bicyclo[1.1.1]pentasilanes: Evaluation of significant interactions between ferrocenyl units and rigid silicon cages

Yusuke Kishimoto, Shintaro Ishida, Takeaki Iwamoto

SCI - Chemistry

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

Ferrocenyl-substituted bicyclo[1.1.1]pentasilanes 1, 2, and 3 were synthesized by the reactions of bromo-substituted bicyclo[1.1.1]pentasilanes with lithioferrocene. Significant interactions between bicyclo[1.1.1]pentasilane and ferrocenyl units were suggested by cyclic voltammetry, UVvis absorption spectrum, and theoretical calculations.

Original language	English
Pages (from-to)	235-237
Number of pages	3
Journal	Chemistry Letters
Volume	45
Issue number	2
DOIs	https://doi.org/10.1246/cl.151089
Publication status	Published - 2016

ASJC Scopus subject areas

Chemistry(all)

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abstract = "Ferrocenyl-substituted bicyclo[1.1.1]pentasilanes 1, 2, and 3 were synthesized by the reactions of bromo-substituted bicyclo[1.1.1]pentasilanes with lithioferrocene. Significant interactions between bicyclo[1.1.1]pentasilane and ferrocenyl units were suggested by cyclic voltammetry, UVvis absorption spectrum, and theoretical calculations.",

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AU - Ishida, Shintaro

AU - Iwamoto, Takeaki

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AB - Ferrocenyl-substituted bicyclo[1.1.1]pentasilanes 1, 2, and 3 were synthesized by the reactions of bromo-substituted bicyclo[1.1.1]pentasilanes with lithioferrocene. Significant interactions between bicyclo[1.1.1]pentasilane and ferrocenyl units were suggested by cyclic voltammetry, UVvis absorption spectrum, and theoretical calculations.

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Ferrocenyl-substituted bicyclo[1.1.1]pentasilanes: Evaluation of significant interactions between ferrocenyl units and rigid silicon cages

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