Ferrimagnetic property of two-dimensional layered compound K[Mn(3-MeOsalen)]2[Cr(CN)6]·H2O

Hitoshi Miyasaka; Hisashi Okawa; Naohide Matsumoto

doi:10.1080/10587259908028874

Ferrimagnetic property of two-dimensional layered compound K[Mn(3-MeOsalen)]₂[Cr(CN)₆]·H₂O

Hitoshi Miyasaka, Hisashi Okawa, Naohide Matsumoto

Research output: Contribution to journal › Conference article › peer-review

1 Citation (Scopus)

Abstract

A series of bimetallic compounds of the general formula K[Mn(3-MeOsalen)]₂[M(CN)₆] (M = Co³⁺, Fe³⁺, Mn³⁺, Cr³⁺) has a similar 2-D network structure but their magnetic properties vary depending upon the nature of the metal ion of [M(CN)₆]^3- and the interlayer magnetic interaction. The magnetic property of K[Mn(3-MeOsalen)]₂[Cr(CN)₆]·H₂O shows a ferrimagnetic nature arising from an intralayer ferrimagnetic ordering due to the antiferromagnetic spin arrangement of neighboring high spin Mn³⁺ and Cr³⁺, and an interlayer ferromagnetic interaction.

Original language	English
Pages (from-to)	1015-1023
Number of pages	9
Journal	Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals
Volume	335
DOIs	https://doi.org/10.1080/10587259908028874
Publication status	Published - 1999
Externally published	Yes
Event	Proceedings of the 1998 6th International Conference on Molecule Based Magnets (ICMM'98) - Seignosse, France Duration: 1998 Sep 12 → 1998 Sep 17

ASJC Scopus subject areas

Condensed Matter Physics

Access to Document

10.1080/10587259908028874

Cite this

Ferrimagnetic property of two-dimensional layered compound K[Mn(3-MeOsalen)]₂[Cr(CN)₆]·H₂O. / Miyasaka, Hitoshi; Okawa, Hisashi; Matsumoto, Naohide.

In: Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, Vol. 335, 1999, p. 1015-1023.

Research output: Contribution to journal › Conference article › peer-review

@article{902365f38f5d4e0da099b37d9f7dd7fa,

title = "Ferrimagnetic property of two-dimensional layered compound K[Mn(3-MeOsalen)]2[Cr(CN)6]·H2O",

abstract = "A series of bimetallic compounds of the general formula K[Mn(3-MeOsalen)]2[M(CN)6] (M = Co3+, Fe3+, Mn3+, Cr3+) has a similar 2-D network structure but their magnetic properties vary depending upon the nature of the metal ion of [M(CN)6]3- and the interlayer magnetic interaction. The magnetic property of K[Mn(3-MeOsalen)]2[Cr(CN)6]·H2O shows a ferrimagnetic nature arising from an intralayer ferrimagnetic ordering due to the antiferromagnetic spin arrangement of neighboring high spin Mn3+ and Cr3+, and an interlayer ferromagnetic interaction.",

author = "Hitoshi Miyasaka and Hisashi Okawa and Naohide Matsumoto",

note = "Funding Information: The authors thank Rigaku Denki Co., Ltd. for help in X-ray powder diffraction analyses. This work was supported by the JSPS Research Fellowships for Young Scientists (H. M.).; Proceedings of the 1998 6th International Conference on Molecule Based Magnets (ICMM'98) ; Conference date: 12-09-1998 Through 17-09-1998",

year = "1999",

doi = "10.1080/10587259908028874",

language = "English",

volume = "335",

pages = "1015--1023",

journal = "Molecular Crystals and Liquid Crystals",

issn = "1542-1406",

publisher = "Taylor and Francis Ltd.",

}

TY - JOUR

T1 - Ferrimagnetic property of two-dimensional layered compound K[Mn(3-MeOsalen)]2[Cr(CN)6]·H2O

AU - Miyasaka, Hitoshi

AU - Okawa, Hisashi

AU - Matsumoto, Naohide

N1 - Funding Information: The authors thank Rigaku Denki Co., Ltd. for help in X-ray powder diffraction analyses. This work was supported by the JSPS Research Fellowships for Young Scientists (H. M.).

PY - 1999

Y1 - 1999

N2 - A series of bimetallic compounds of the general formula K[Mn(3-MeOsalen)]2[M(CN)6] (M = Co3+, Fe3+, Mn3+, Cr3+) has a similar 2-D network structure but their magnetic properties vary depending upon the nature of the metal ion of [M(CN)6]3- and the interlayer magnetic interaction. The magnetic property of K[Mn(3-MeOsalen)]2[Cr(CN)6]·H2O shows a ferrimagnetic nature arising from an intralayer ferrimagnetic ordering due to the antiferromagnetic spin arrangement of neighboring high spin Mn3+ and Cr3+, and an interlayer ferromagnetic interaction.

AB - A series of bimetallic compounds of the general formula K[Mn(3-MeOsalen)]2[M(CN)6] (M = Co3+, Fe3+, Mn3+, Cr3+) has a similar 2-D network structure but their magnetic properties vary depending upon the nature of the metal ion of [M(CN)6]3- and the interlayer magnetic interaction. The magnetic property of K[Mn(3-MeOsalen)]2[Cr(CN)6]·H2O shows a ferrimagnetic nature arising from an intralayer ferrimagnetic ordering due to the antiferromagnetic spin arrangement of neighboring high spin Mn3+ and Cr3+, and an interlayer ferromagnetic interaction.

UR - http://www.scopus.com/inward/record.url?scp=0033335606&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0033335606&partnerID=8YFLogxK

U2 - 10.1080/10587259908028874

DO - 10.1080/10587259908028874

M3 - Conference article

AN - SCOPUS:0033335606

VL - 335

SP - 1015

EP - 1023

JO - Molecular Crystals and Liquid Crystals

JF - Molecular Crystals and Liquid Crystals

SN - 1542-1406

T2 - Proceedings of the 1998 6th International Conference on Molecule Based Magnets (ICMM'98)

Y2 - 12 September 1998 through 17 September 1998

ER -

Ferrimagnetic property of two-dimensional layered compound K[Mn(3-MeOsalen)]₂[Cr(CN)₆]·H₂O

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this