TY - JOUR
T1 - Facile synthesis, spectroscopic and electrochemical properties, and theoretical calculations of porphyrin dimers with a bridging amide-bonded xanthene moiety
AU - Liang, X.
AU - Xu, L.
AU - Li, Minzhi
AU - Mack, John
AU - Stone, Justin
AU - Nyokong, Tebello
AU - Jiang, Y.
AU - Kobayashi, Nagao
AU - Zhu, Weihua
PY - 2015
Y1 - 2015
N2 - A free base porphyrin dimer bridged by a flexible amide-bonded xanthene moiety and its binuclear zinc(II) complex zinc(II) complex were synthesized and characterized. Structural characterization by MS and 1H NMR spectroscopy confirmed the bridged porphyrin dimer structure. The properties of the dimers were characterized by IR, UV-visible absorption, fluorescence and magnetic circular dichroism (MCD) spectroscopy, and electrochemistry studies. Theoretical calculations were carried out to analyze the electronic structures of porphyrin dimers with a bridging amide-bonded xanthene moiety.
AB - A free base porphyrin dimer bridged by a flexible amide-bonded xanthene moiety and its binuclear zinc(II) complex zinc(II) complex were synthesized and characterized. Structural characterization by MS and 1H NMR spectroscopy confirmed the bridged porphyrin dimer structure. The properties of the dimers were characterized by IR, UV-visible absorption, fluorescence and magnetic circular dichroism (MCD) spectroscopy, and electrochemistry studies. Theoretical calculations were carried out to analyze the electronic structures of porphyrin dimers with a bridging amide-bonded xanthene moiety.
UR - http://www.scopus.com/inward/record.url?scp=84929429462&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84929429462&partnerID=8YFLogxK
U2 - 10.1142/S1088424615500492
DO - 10.1142/S1088424615500492
M3 - Article
JO - Journal of Porphyrins and Phthalocyanines
JF - Journal of Porphyrins and Phthalocyanines
SN - 1088-4246
ER -