Facile Multiple Alkylations of C60 Fullerene

Kazuhira Miwa; Shinobu Aoyagi; Takahiro Sasamori; Shogo Morisako; Hiroshi Ueno; Yutaka Matsuo; Hideki Yorimitsu

doi:10.3390/molecules27020450

Facile Multiple Alkylations of C60 Fullerene

Kazuhira Miwa, Shinobu Aoyagi, Takahiro Sasamori, Shogo Morisako, Hiroshi Ueno, Yutaka Matsuo, Hideki Yorimitsu

Creative Interdisciplinary Research Division

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Abstract

The reduction of fullerene (C60) with sodium dispersion in the presence of an excess amount of dipropyl sulfate was found to yield highly propylated fullerene, C60(nC3H7)n (max. n = 24), and C60(nC3H7)20 was predominantly generated as determined by mass spectroscopy.

Original language	English
Article number	450
Journal	Molecules
Volume	27
Issue number	2
DOIs	https://doi.org/10.3390/molecules27020450
Publication status	Published - 2022 Jan 1

Keywords

Alkylation
C60
Dialkyl sulfate
Fullerene
Sodium dispersion

ASJC Scopus subject areas

Analytical Chemistry
Chemistry (miscellaneous)
Molecular Medicine
Pharmaceutical Science
Drug Discovery
Physical and Theoretical Chemistry
Organic Chemistry

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10.3390/molecules27020450

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title = "Facile Multiple Alkylations of C60 Fullerene",

abstract = "The reduction of fullerene (C60) with sodium dispersion in the presence of an excess amount of dipropyl sulfate was found to yield highly propylated fullerene, C60(nC3H7)n (max. n = 24), and C60(nC3H7)20 was predominantly generated as determined by mass spectroscopy.",

keywords = "Alkylation, C60, Dialkyl sulfate, Fullerene, Sodium dispersion",

author = "Kazuhira Miwa and Shinobu Aoyagi and Takahiro Sasamori and Shogo Morisako and Hiroshi Ueno and Yutaka Matsuo and Hideki Yorimitsu",

note = "Funding Information: Funding: This research was funded by JSPS KAKENHI grants 19H02705, 21K14607, 19H02749, and 21H01737 from MEXT (Japan), and JST CREST grant JPMJCR19R4. Publisher Copyright: {\textcopyright} 2022 by the authors. Licensee MDPI, Basel, Switzerland.",

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doi = "10.3390/molecules27020450",

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T1 - Facile Multiple Alkylations of C60 Fullerene

AU - Miwa, Kazuhira

AU - Aoyagi, Shinobu

AU - Sasamori, Takahiro

AU - Morisako, Shogo

AU - Ueno, Hiroshi

AU - Matsuo, Yutaka

AU - Yorimitsu, Hideki

N1 - Funding Information: Funding: This research was funded by JSPS KAKENHI grants 19H02705, 21K14607, 19H02749, and 21H01737 from MEXT (Japan), and JST CREST grant JPMJCR19R4. Publisher Copyright: © 2022 by the authors. Licensee MDPI, Basel, Switzerland.

PY - 2022/1/1

Y1 - 2022/1/1

N2 - The reduction of fullerene (C60) with sodium dispersion in the presence of an excess amount of dipropyl sulfate was found to yield highly propylated fullerene, C60(nC3H7)n (max. n = 24), and C60(nC3H7)20 was predominantly generated as determined by mass spectroscopy.

AB - The reduction of fullerene (C60) with sodium dispersion in the presence of an excess amount of dipropyl sulfate was found to yield highly propylated fullerene, C60(nC3H7)n (max. n = 24), and C60(nC3H7)20 was predominantly generated as determined by mass spectroscopy.

KW - Alkylation

KW - C60

KW - Dialkyl sulfate

KW - Fullerene

KW - Sodium dispersion

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Facile Multiple Alkylations of C60 Fullerene

Abstract

Keywords

ASJC Scopus subject areas

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