Facile isomerization of a tungsten silyl complex to a base-stabilized silylene complex via 1,2-migration of an aryl group

Masaaki Okazaki, Eiji Suzuki, Norito Miyajima, Hiromi Tobita, Hiroshi Ogino

Research output: Contribution to journalArticlepeer-review

22 Citations (Scopus)

Abstract

Irradiation of Cp*(CO)3WMe in the presence of N,N-dimethyl-2-(dimethylsilyl)aniline led to the intermediate formation of Cp*(CO)2W{κ2(Si,N)-Me2 N(o-C6H4SiMe2)} (3), which was converted to the base-stabilized silylene complex Cp*(CO)2W{κ2 (Si,C)-SiMe2-NMe2(o-C6H4)} (2) through 1,2-migration of the aryl group.

Original languageEnglish
Pages (from-to)4633-4635
Number of pages3
JournalOrganometallics
Volume22
Issue number23
DOIs
Publication statusPublished - 2003 Nov 10

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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