TY - JOUR
T1 - Fabrication of polymer organized thin films containing ruthenium complexes
AU - Miyashita, Tokuji
AU - Chen, Jinfeng
AU - Yuasa, Masahiro
AU - Mitsuishi, Masaya
N1 - Copyright:
Copyright 2020 Elsevier B.V., All rights reserved.
PY - 1999
Y1 - 1999
N2 - Polyion complex Langmuir-Blodgett (LB) films containing Ru(dpphen)32+ (dpphen = 4,7-diphenyl-1,10-phenanthroline) probe (Rudpphen) were prepared by spreading a mixed chloroform solution of N-dodecylacrylamide (DDA)-N-acryloxysuccinimide (SuOA) copolymer and Ru(dpphen)3Cl2, onto the water subphase at pH = 11. The SuOA groups undergo a hydrolysis at pH = 11 yielding the acrylate anion, which forms an ion-complex with Ru(dpphen)32+ in the monolayer. It was found that Ru(dpphen)32+ is located in the hydrophobic portion of the monolayer at the air/water interface. The monolayers of p(DDA/Rudpphen) could be successfully transferred on a quartz substrate with less than 14 mol% Ru(dpphen)32+ content. The UV-vis spectroscopy and X-ray diffraction confirmed that the Ru(dpphen)32+ molecules were densely packed and uniformly distributed in the polyion complex LB films. The properties of p(DDA/Rudpphen) monolayer and LB films were compared with p(DDA/Rubpy) LB films (bpy = 2,2′-bipyridine), which have been previously reported. The luminescence quenching of Ru(dpphen)32+ by oxygen was also discussed.
AB - Polyion complex Langmuir-Blodgett (LB) films containing Ru(dpphen)32+ (dpphen = 4,7-diphenyl-1,10-phenanthroline) probe (Rudpphen) were prepared by spreading a mixed chloroform solution of N-dodecylacrylamide (DDA)-N-acryloxysuccinimide (SuOA) copolymer and Ru(dpphen)3Cl2, onto the water subphase at pH = 11. The SuOA groups undergo a hydrolysis at pH = 11 yielding the acrylate anion, which forms an ion-complex with Ru(dpphen)32+ in the monolayer. It was found that Ru(dpphen)32+ is located in the hydrophobic portion of the monolayer at the air/water interface. The monolayers of p(DDA/Rudpphen) could be successfully transferred on a quartz substrate with less than 14 mol% Ru(dpphen)32+ content. The UV-vis spectroscopy and X-ray diffraction confirmed that the Ru(dpphen)32+ molecules were densely packed and uniformly distributed in the polyion complex LB films. The properties of p(DDA/Rudpphen) monolayer and LB films were compared with p(DDA/Rubpy) LB films (bpy = 2,2′-bipyridine), which have been previously reported. The luminescence quenching of Ru(dpphen)32+ by oxygen was also discussed.
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U2 - 10.1295/polymj.31.1121
DO - 10.1295/polymj.31.1121
M3 - Article
AN - SCOPUS:0033322826
VL - 31
SP - 1121
EP - 1126
JO - Polymer Journal
JF - Polymer Journal
SN - 0032-3896
IS - 11 pt 2
ER -