Fabrication of photochemical pattern on a self-assembled monolayer (SAM) of a ruthenium cluster under electrochemical control

Yi Zhang, Yujin Tong, Masaaki Abe, Kohei Uosaki, Masatoshi Osawa, Yoichi Sasaki, Shen Ye

Research output: Contribution to journalArticle

21 Citations (Scopus)

Abstract

A new strategy is proposed for the fabrication of photochemical pattern of a self-assembled monolayer (SAM) of an oxo-centered tri-ruthenium (Ru 3) cluster on a gold electrode surface. The fabrication was achieved under combined photochemical and electrochemical controls. By this strategy, the patterned SAM surfaces terminated with different kinds of moiety groups such as carbon monoxide (CO), nitric oxide (NO) and a successive layer of Ru 3 cluster by ligand-exchange reaction are obtained with high yields.

Original languageEnglish
Pages (from-to)261-267
Number of pages7
JournalJournal of Materials Chemistry
Volume19
Issue number2
DOIs
Publication statusPublished - 2009 Jan 1
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Chemistry

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