Fabrication of photochemical pattern on a self-assembled monolayer (SAM) of a ruthenium cluster under electrochemical control

Yi Zhang; Yujin Tong; Masaaki Abe; Kohei Uosaki; Masatoshi Osawa; Yoichi Sasaki; Shen Ye

doi:10.1039/b815571b

Fabrication of photochemical pattern on a self-assembled monolayer (SAM) of a ruthenium cluster under electrochemical control

Yi Zhang, Yujin Tong, Masaaki Abe, Kohei Uosaki, Masatoshi Osawa, Yoichi Sasaki, Shen Ye

Research output: Contribution to journal › Article › peer-review

21 Citations (Scopus)

Abstract

A new strategy is proposed for the fabrication of photochemical pattern of a self-assembled monolayer (SAM) of an oxo-centered tri-ruthenium (Ru ₃) cluster on a gold electrode surface. The fabrication was achieved under combined photochemical and electrochemical controls. By this strategy, the patterned SAM surfaces terminated with different kinds of moiety groups such as carbon monoxide (CO), nitric oxide (NO) and a successive layer of Ru ₃ cluster by ligand-exchange reaction are obtained with high yields.

Original language	English
Pages (from-to)	261-267
Number of pages	7
Journal	Journal of Materials Chemistry
Volume	19
Issue number	2
DOIs	https://doi.org/10.1039/b815571b
Publication status	Published - 2009
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)
Materials Chemistry

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abstract = "A new strategy is proposed for the fabrication of photochemical pattern of a self-assembled monolayer (SAM) of an oxo-centered tri-ruthenium (Ru 3) cluster on a gold electrode surface. The fabrication was achieved under combined photochemical and electrochemical controls. By this strategy, the patterned SAM surfaces terminated with different kinds of moiety groups such as carbon monoxide (CO), nitric oxide (NO) and a successive layer of Ru 3 cluster by ligand-exchange reaction are obtained with high yields.",

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AU - Zhang, Yi

AU - Tong, Yujin

AU - Abe, Masaaki

AU - Uosaki, Kohei

AU - Osawa, Masatoshi

AU - Sasaki, Yoichi

AU - Ye, Shen

PY - 2009

Y1 - 2009

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AB - A new strategy is proposed for the fabrication of photochemical pattern of a self-assembled monolayer (SAM) of an oxo-centered tri-ruthenium (Ru 3) cluster on a gold electrode surface. The fabrication was achieved under combined photochemical and electrochemical controls. By this strategy, the patterned SAM surfaces terminated with different kinds of moiety groups such as carbon monoxide (CO), nitric oxide (NO) and a successive layer of Ru 3 cluster by ligand-exchange reaction are obtained with high yields.

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SN - 0959-9428

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Fabrication of photochemical pattern on a self-assembled monolayer (SAM) of a ruthenium cluster under electrochemical control

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