@article{17be8fc21b5448f78029ccdd918b570e,
title = "Fabrication of hydrophobic polymethylsilsesquioxane aerogels by a surfactant-free method using alkoxysilane with ionic group",
abstract = "Phase separation control is an important factor to prepare a porous monolith by an aqueous sol–gel reaction. Here, we report a surfactant-free synthesis method to obtain hydrophobic polymethylsilsesquioxane aerogels by copolymerizing a cationic-functionalized alkoxysilane N-trimethoxysilylpropyl-N,N,N-trimethylammonium chloride. The resultant materials have low-density, high visible-light transmittance, and high thermal insulating equivalent to those of prepared under the presence of surfactant.",
keywords = "Aerogels, Polysilsesquioxanes, Porous materials, Sol–gel, Surfactant-free",
author = "Gen Hayase and Shuya Nagayama and Kazuya Nonomura and Kazuyoshi Kanamori and Ayaka Maeno and Hironori Kaji and Kazuki Nakanishi",
note = "Funding Information: This study was carried out with the NMR spectrometer in the JURC at the Institute for Chemical Research, Kyoto University. Financial support from a Grant-in-Aid for Scientific Research (KAKENHI, No. 15K17909 and 25·1089 ) administrated by the Japan Society for the Promotion of Science (JSPS) and the Ministry of Education, Culture, Sports, Science and Technology (MEXT) , Japan. Also, partially supported by Advanced Low Carbon Technology Research and Development Program (ALCA) administrated by Japan Science and Technology Agency (JST). Funding Information: This study was carried out with the NMR spectrometer in the JURC at the Institute for Chemical Research, Kyoto University. Financial support from a Grant-in-Aid for Scientific Research (KAKENHI, No. 15K17909 and 25?1089) administrated by the Japan Society for the Promotion of Science (JSPS) and the Ministry of Education, Culture, Sports, Science and Technology (MEXT), Japan. Also, partially supported by Advanced Low Carbon Technology Research and Development Program (ALCA) administrated by Japan Science and Technology Agency (JST). Publisher Copyright: {\textcopyright} 2017 The Ceramic Society of Japan and the Korean Ceramic Society",
year = "2017",
month = jun,
doi = "10.1016/j.jascer.2017.02.003",
language = "English",
volume = "5",
pages = "104--108",
journal = "Journal of Asian Ceramic Societies",
issn = "2187-0764",
publisher = "Elsevier BV",
number = "2",
}