Expeditious construction of the DEF ring system of thiersinine B

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    10 Citations (Scopus)

    Abstract

    Figure presented. Construction of a DEF ring model of thiersinine B has been achieved from a Wieland-Miescher ketone derivative by a five-step sequence featuring a one-pot regioselective α-allylation of the starting α,β-unsaturated ketone via the Claisen rearrangement and a double dihydroxylation of a dienone intermediate.

    Original languageEnglish
    Pages (from-to)6286-6289
    Number of pages4
    JournalJournal of Organic Chemistry
    Volume75
    Issue number18
    DOIs
    Publication statusPublished - 2010 Sep 17

    ASJC Scopus subject areas

    • Organic Chemistry

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